206752-10-5

Basic information

• Product Name: dimethyl 2-benzoyl-2-(3-oxobutyl)malonate
• Synonyms: dimethyl 2-benzoyl-2-(3-oxobutyl)malonate
• CAS NO: 206752-10-5
• Molecular Weight: 306.315
• Mol File: 206752-10-5.mol

Chemical Properties

• CAS DataBase Reference: dimethyl 2-benzoyl-2-(3-oxobutyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-benzoyl-2-(3-oxobutyl)malonate(206752-10-5)
• EPA Substance Registry System: dimethyl 2-benzoyl-2-(3-oxobutyl)malonate(206752-10-5)

Safety Data

• Hazardous Substances Data: 206752-10-5(Hazardous Substances Data)

Upstream product

• 24821-06-5 dimethyl 2-benzoylmalonate 
• 78-94-4 methyl vinyl ketone 
• 98-88-4 benzoyl chloride 
• 108-59-8 malonic acid dimethyl ester 

Downstream Products

• 300849-29-0 C₁₆H₁₈O₆ 

Relevant articles and documents

Molecular structure and O-H?O hydrogen bond in 1-aryl-1,3-diketone malonates

The molecular structure of four 1,3-diketone malonates 1-4 were studied by analysis of geometric parameters obtained from single crystal X-ray diffraction experiments at 293 K, displaying three sections: aromatic ring (4-substituted phenyl or naphthyl rin

Synthesis of 1-aryl-1,3-diketones containing the dimethyl malonate moiety

The synthesis of new 1,3-diketones malonates 3 a-j were prepared in good yield from 1,5-diketones 2 a-j by employing the 1,5 → 1,3 diketone rearrangement.

A simple 1,5 → 1,3-diketone rearrangement

1-Aryl-1,3-diketones 4-7 were prepared by reaction of the corresponding 1-aryl-1,5-diketones 2b with piperidinium acetate in refluxing C6H6.