20699-69-8

Basic information

• Product Name: [diphenylmanganese]
• Synonyms: [diphenylmanganese]
• CAS NO: 20699-69-8
• Molecular Weight: 209.149
• Mol File: 20699-69-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [diphenylmanganese](CAS DataBase Reference)
• NIST Chemistry Reference: [diphenylmanganese](20699-69-8)
• EPA Substance Registry System: [diphenylmanganese](20699-69-8)

Safety Data

• Hazardous Substances Data: 20699-69-8(Hazardous Substances Data)

Upstream product

• 591-51-5 phenyllithium 
• 42599-17-7 (E)-1-iodo-1-octene 
• 106865-24-1 (Z)-5-Iodo-5-decene 
• 104293-08-5 (5E)-5-iodo-dec-5-ene 
• 76346-98-0 (Z)-(1-iodo-1-hexenyl)trimethylsilane 
• 66270-63-1 [(1E)-1-iodo-hex-1-enyl]-trimethyl-silane 
• 92682-58-1 (Z)-1-iodo-2-pentyl-1,4-pentadiene 
• 101349-79-5 2-phenylvinyl iodide 
• 127462-37-7 1-iodo-2-propyl-1-pentene 
• 17497-53-9 1-iodo-1-cyclohexene 
• 66688-59-3 2-iodo-1-pentene 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 92-52-4 biphenyl 
• 2553-19-7 diethoxydiphenylsilane 
• 780-69-8 triethoxyphenylsilane 
• 2996-92-1 phenyl trimethylsiloxane 
• 6843-66-9 dimethoxy(diphenyl)silane 
• 75-76-3 tetramethylsilane 
• 770-09-2 benzyltrimethylsilane 
• 23304-58-7 (1,1′-bicyclohexyl)-3,3′-dione 
• 591-24-2 3-Methylcyclohexanone 

Relevant articles and documents

METHOD FOR THE PREPARATION OF A COMPOUND OF THE GENERAL FORMULA R1-R1 AND/OR R1-R2 USING HOMO AND HETERO COUPLING REACTIONS

The present application relates to a method for the preparation of a compound of the general formula R1-R2 (I) and/or R1-R1 (II) comprising providing a compound of the general formula R1dM1Am.zM4Zn (III) or R1R2M1R3kAm.xM4Zn (IV) or R1M1R2R3kM2Am.xM4Zn (V) or R1M3R2M1.xM4Zn (VI) and reacting this compound III-VI with a quinone to produce a compound of the general formula (I) or (II) or a mixture of compounds (I) and (II). The coupling reaction can be used to prepare homo and/or hetero coupling products from well known starting materials using a quinone as redox reagent. The quinone may be recycled from the reaction.

TRANSITION METAL ?-COMPLEXES IN ORGANIC SYNTHESIS 5. CROSS-COUPLING OF ORGANOMANGANESE COMPOUNDS WITH ALKENYL IODIDES

Aryl organomanganese compounds ArMnX and Ph3MnLi (Ar = Ph, p-MeC6H4, p-MeOC6H4, p-ClC6H4, p-BrC6H4, α-naphthyl; X = Cl, Br) react with alkenyl iodides RR1C=CR2I (R = H, Pr, Bu, i-Bu, C6H13, CH2=CHCH2, Ph; R1 = H, Pr, C5H11; R2 = H, Pr, SiMe3) in THF at 0-20 deg C to give cross-coupling products RR1C=CR2Ar in high yields.