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Kinetics and Mechanism of the Alkaline Hydrolysis of 2,4-Dinitrophenyl 4′-Hydroxyphenylpropiolate
Cevasco, Giorgio,Pardini, Roberto,Thea, Sergio
, p. 665 - 669 (2007/10/03)
The alkaline hydrolysis of the title ester was studied in 40 % dioxane/water (v/v) solutions. Kinetic data, reactivity comparisons with model substrates and activation parameters appear to suggest the occurrence of a dissociative E1cB pathway although participation of the associative mechanism cannot be definitely ruled out.
