207461-13-0

Upstream product

• 207461-11-8 8-bromo-2-chloro-1,10-phenanthroline 
• 5720-07-0 4-methoxyphenylboronic acid 
• 207461-12-9 3-bromo-9-iodo-1,10-phenanthroline 
• 7089-68-1 2-chloro-[1,10]phenanthroline 

Downstream Products

• 337527-48-7 2,2'-dianisyl-8,8'-bis-1,10-phenanthroline 

Relevant academic research and scientific papers

Synthesis of unsymmetrical 2,8- and 2,9-dihalo-1,10-phenanthrolines and derivatives

A general method for the preparation of the unsymmetrical 2,8- and 2,9- dihalophenanthrolines is presented. The use of these halophenanthrolines as synthetic substrates in the Suzuki and Sonogashira/Castro-Stevens palladium catalyzed chemistry is exemplifed. The derivatized phenanthrolines are seen as key building blocks for the design and construction of topologically complex polynuclear metal coordination complexes.