Tetrahedron Letters p. 2697 - 2700 (1998)
Update date:2022-08-03
Topics:
Toyota, Shinji
Woods, Craig R.
Benaglia, Maurizio
Siegel, Jay S.
A general method for the preparation of the unsymmetrical 2,8- and 2,9- dihalophenanthrolines is presented. The use of these halophenanthrolines as synthetic substrates in the Suzuki and Sonogashira/Castro-Stevens palladium catalyzed chemistry is exemplifed. The derivatized phenanthrolines are seen as key building blocks for the design and construction of topologically complex polynuclear metal coordination complexes.
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