Synthesis of unsymmetrical 2,8- and 2,9-dihalo-1,10-phenanthrolines and derivatives

DOI: 10.1016/S0040-4039(98)00409-2

Source and publish data:

Tetrahedron Letters p. 2697 - 2700 (1998)

Update date:2022-08-03

Topics:

Authors:

Toyota, Shinji

Woods, Craig R.

Benaglia, Maurizio

Siegel, Jay S.

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Article abstract of DOI:10.1016/S0040-4039(98)00409-2

A general method for the preparation of the unsymmetrical 2,8- and 2,9- dihalophenanthrolines is presented. The use of these halophenanthrolines as synthetic substrates in the Suzuki and Sonogashira/Castro-Stevens palladium catalyzed chemistry is exemplifed. The derivatized phenanthrolines are seen as key building blocks for the design and construction of topologically complex polynuclear metal coordination complexes.

Full text of DOI:10.1016/S0040-4039(98)00409-2

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