207564-33-8

Upstream product

• 58871-10-6 3,4-di-O-benzyl-D-glucal 
• 87316-22-1 (2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 
• 100-39-0 benzyl bromide 
• 137792-57-5 3,4-di-O-benzyl-6-O-(tert-butyldiphenylsilyl)-D-glucal 
• 13265-84-4 D-glucal 
• 129840-37-5 1,5-anhydro-3,4-di-O-benzyl-6-O-(tert-butyldimethylsilyl)-2-deoxy-D-arabino-hex-1-enitol 
• 136656-49-0 3,4-di-O-acetyl-1,5-anhydro-6-O-t-butyldimethylsilyl-2-deoxy-D-arabino-hex-1-enitol 
• 82295-98-5 3,4-di-O-acetyl-1,5-anhydro-2-deoxy-D-arabino-hex-1-enitol 
• 2873-29-2 D-glucal triacetate 

Downstream Products

• 207564-32-7 1,5-anhydro-di-O-benzyl-2,6,7-trideoxy-D-arabino-hept-1,6-dienitol 
• 1253943-82-6 methyl 2,6-anhydro-3,4-di-O-benzyl-5-deoxy-D-lyxohex-5-enonate 
• 1295541-45-5 methyl 2,6-anhydro-3,4-di-O-benzyl-5-deoxy-5-nitro-D-lyxohex-5-enonate 
• 1295541-47-7 methyl (6R)-2,6-anhydro-3,4-di-O-benzyl-5-deoxy-6-(dimethoxyphosphoryl)-5-nitro-D-gluconate 
• 1295541-48-8 methyl (6R)-2,6-anhydro-3,4-di-O-benzyl-5-deoxy-6-(dimethoxyphosphoryl)-5-acetamido-D-gluconate 
• 1236311-60-6 C₂₉H₄₄O₅Si 
• 1192260-17-5 1-O-acetyl-3,4-di-O-benzyl-6-O-thexyldimethylsilyl-5a-carba-α-D-glucopyranose 
• 120927-60-8 Ethyl (α-p-Methoxybenzyl 3,4-di-O-benzyl-6-O-(tert-butyldimethylsilyl)-2,7,8-trideoxy-2-iodo-D-manno-L-glycero-non-7-eno-1,5-pyranos)uronate 
• 120927-59-5 Ethyl (α-p-Methoxybenzyl 3,4-di-O-benzyl-6-O-(tert-butyldimethylsilyl)-2,7,8-trideoxy-2-iodo-D-manno-D-glycero-non-7-eno-1,5-pyranos)uronate 

Relevant academic research and scientific papers

Carbocyclic Substrate Analogues Reveal Kanosamine Biosynthesis Begins with the α-Anomer of Glucose 6-Phosphate

NtdC is an NAD-dependent dehydrogenase that catalyzes the conversion of glucose 6-phosphate (G6P) to 3-oxo-glucose 6-phosphate (3oG6P), the first step in kanosamine biosynthesis in Bacillus subtilis and other closely-related bacteria. The NtdC-catalyzed r

Synthesis and preliminary biological evaluation of carba analogues from Neisseria meningitidis A capsular polysaccharide

The Gram-negative encapsulated bacterium Neisseria meningitidis type A (MenA) is a major cause of meningitis in developing countries, especially in the sub-Saharan region of Africa. The development and manufacture of an efficient glycoconjugate vaccine ag

Accessing C-1 phosphonylated 2-acylamino uronic acids via 2-nitro-glycals

Two approaches are described for the synthesis of 2-acylamino uronic acid glycosyl phosphonates from readily accessible d-glucal. The first approach that entailed oxidation of the C-6 hydroxyl group followed by phosphonylation of the uronate 2-nitro-glycal, resulted in the formation of the β-l-gulo- configured phosphonate. Reversing the reaction order resulted in the exclusive formation of the β-d-gluco-configured phosphonate. In both cases the thermodynamic 1,2-trans-di-equatorial phosphonylation product is obtained.

Carbohydrates to carbocycles: An expedient synthesis of pseudo-sugars

A short and versatile synthesis of pseudo-sugars from sugars utilizing the Claisen rearrangement as the key step is described.

A Divergent Route for a Total Synthesis of Cyclophellitol and Epicyclophellitol from a Oxabicyclic Glycoside Prepared from D-Glucal

D-Glucal has been used for syntheses of Tatsuta's penultimate intermediate for cyclophellitol and epicyclophellitol via a 6-exo-trig radical cyclization of 2-deoxy-2-iodo-6-alkynyl glycoside, the diastereomeric mixture produced thereby being separated into two sets, each of which leads to one or other target materials.

Radical Cyclization Routes to Bridged Pyranosides as Precursors of Densely Functionalized Cycloalkanes

Glycals derived from hexapyranoses permit the incorporation of iodine at C-2 as well as elaboration of an olefinic residue via the C-5-hydroxymethyl group.Radical cyclization of these functionalities leads to bicyclic systems whose bridge sizes depend on