20782-94-9Relevant articles and documents
Synthesis method of halogenated aniline
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Paragraph 0156-0158, (2020/08/09)
The invention provides a synthesis method of halogenated aniline. The synthesis method comprises the following steps: taking a carbon-coated nickel nano composite material containing alkaline-earth metals as a catalyst, and catalyzing a hydrogenation reduction reaction of halogenated nitrobenzene in a hydrogen atmosphere, wherein the nano composite material contains a core-shell structure with a shell layer and an inner core, the shell layer is a graphitized carbon layer containing alkaline-earth metals and oxygen, and the inner core is nickel nano particles. According to the method, the nanocomposite material is used as a catalyst; a carbon material and the nickel nano particles generate a synergistic effect and a good catalytic effect, the alkaline-earth metals of the shell layer further synergistically improve the catalytic performance of the nano composite material, and the catalyst is used for hydrogenation reduction of halogenated nitrobenzene to synthesize halogenated aniline,has excellent activity, selectivity and safety, and can effectively solve the dehalogenation problem in the reaction process.
Synthesis method of halogenated aniline
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Paragraph 0103; 0140-0142, (2020/08/09)
The invention provides a synthesis method of halogenated aniline. The synthesis method comprises the following steps: taking a carbon-coated nickel nano composite material containing alkaline-earth metals as a catalyst, and catalyzing a hydrogenation reduction reaction of halogenated nitrobenzene in a hydrogen atmosphere; wherein the nano composite material contains a core-shell structure with a shell layer and an inner core, the shell layer is a graphitized carbon layer containing alkaline-earth metals, nitrogen and oxygen, and the inner core is nickel nano particles. According to the method,the nano composite material is used as a catalyst; a carbon material and the nickel nano particles generate a synergistic effect and a good catalytic effect, the alkaline-earth metals of the shell layer further synergistically improve the catalytic performance of the nano composite material, and the catalyst is used for hydrogenation reduction of halogenated nitrobenzene to synthesize halogenatedaniline, has excellent activity, selectivity and safety, and can effectively solve the dehalogenation problem in the reaction process.