20907-27-1Relevant academic research and scientific papers
An approach to α-keto vinyl carbinols
Braun, Marie-Gabrielle,Zard, Samir Z.
, p. 776 - 779 (2011/04/24)
Adducts from the radical addition of xanthates to ethyl vinyl sulfide readily undergo elimination of the xanthate group upon thermolysis to give vinylic and/or allylic sulfides, depending on the structure. In the case of α-xanthyl ketones, the adducts are converted into α-keto vinyl carbinols by rearrangement of the sulfoxides derived from the vinylic and allylic sulfides.
Application of Cyanophosphates in Organic Synthesis. Reactivity of α-Cyano-α-diethylphosphonooxy Anions
Kurihara, Takushi,Santo, Kazunori,Harusawa, Shinya,Yoneda, Ryuji
, p. 4777 - 4788 (2007/10/02)
The utility of the cyanohydrin diethylphosphates derived from aldehydes (arylaldehydes,crotonaldehyde, and cinnamaldehyde) as an acyl anion equivalent was examined.Deprotonation of cyanophosphates with n-butyllithium in the presence of tetramethylethylene
REACTION DU CHLOROALLYLLITHIUM ET DU gem-CHLORO(METHYL)ALLYLLITHIUM SUR LES ESTERS: NOUVELLE METHODE DE SYNTHESE DE CETONES CHLOREES ETHYLENIQUES ET D'ACYLOINES ETHYLENIQUES
Mauze, B.,Doucoure, A.,Miginiac, I.
, p. 1 - 8 (2007/10/02)
Chloroallyllithium and gem-chloro(methyl)allyllithium readily react with aliphatic and aromatic esters to produce α- and γ-chlorinated α- and β-ethylenic ketones, and α-ethylenic acyloins, according to the hydrolysis conditions.
