20912-17-8

Basic information

• Product Name: Benzene, 1-[(4-methylphenyl)thio]-2-nitro-
• CAS NO: 20912-17-8
• Molecular Formula: C13H11NO2S
• Molecular Weight: 245.302
• Mol File: 20912-17-8.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(4-methylphenyl)thio]-2-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(4-methylphenyl)thio]-2-nitro-(20912-17-8)
• EPA Substance Registry System: Benzene, 1-[(4-methylphenyl)thio]-2-nitro-(20912-17-8)

Safety Data

• Hazardous Substances Data: 20912-17-8(Hazardous Substances Data)

Upstream product

• 10486-08-5 sodium p-thiocresolate 
• 88-73-3 2-Chloronitrobenzene 
• 577-19-5 2-nitrophenyl bromide 
• 106-45-6 para-thiocresol 
• 31614-66-1 tributyl(p-tolyl)stannane 
• 7669-54-7 2-nitrobenzenesulfenyl chloride 
• 497-19-8 sodium carbonate 
• 5455-59-4 2-Nitrobenzenesulfonamide 
• 1493-27-2 ortho-nitrofluorobenzene 
• 552-16-9 ortho-nitrobenzoic acid 
• 103-19-5 di(p-tolyl) disulfide 
• 528-29-0 1,2-Dinitrobenzene 
• 609-73-4 o-nitroiodobenzene 

Downstream Products

• 29787-26-6 4'-Tolyl-2-nitrosophenylsulfon 
• 1213-33-8 o-aminophenyl p-tolyl sulfone 
• 61174-45-6 2-Azidophenyl-4-tolylsulfon 
• 1220-92-4 1-nitro-2-tosylbenzene 
• 29787-22-2 4'-Tolyl-2-nitrophenylsulfoxid 
• 126616-89-5 C₁₃H₁₀BrNO₂S 
• 126585-08-8 4-(2-nitro phenylthio)benzaldehyde 
• 126585-07-7 4-(2-nitro phenylthio)benzoic acid 
• 58696-23-4 (2-Ethylsulfanyl-phenyl)-p-tolyl-phosphoramidic acid diethyl ester 
• 3939-47-7 3-methyl-10H-phenothiazine 
• 16452-09-8 (2-aminophenyl)-4’-methylphenyl sulfide 
• 126616-84-0 Acetic acid 4-[2-(2-diethylamino-acetylamino)-phenylsulfanyl]-benzyl ester 
• 126584-88-1 Acetic acid 4-[2-(4-chloro-benzoylamino)-phenylsulfanyl]-benzyl ester 
• 126646-35-3 Acetic acid 4-[2-(2-chloro-acetylamino)-phenylsulfanyl]-benzyl ester 

Relevant articles and documents

Coupling of thiols and aromatic halides promoted by diboron derived super electron donors

We have proven that pyridine-boryl complexes can be used as superelectron donors to promote the coupling of thiols and aromatic halides through a SRN1 mechanism. The reaction is efficient for a broad substrate scope, tolerating heterocycles including pyridines, enolizable or reducible functional groups. The method has been applied to intermediates in drug synthesis as well as interesting functionalized polythioethers through a controlled and consecutive intramolecular electron transfer process.

C-S coupling with nitro group as leaving group via simple inorganic salt catalysis

An efficient and practical synthetic protocol to synthesize nonsymmetrical aryl thioethers by nucleophilic aromatic substitution (SNAr) reaction of nitroarenes by thiols with potassium phosphate as the catalyst is described. Various moderate to strong electron-withdrawing functional groups are tolerated by the system to provide thioethers in a good to excellent yields. We also showed that the present method allows access to 3 drug examples in a short reaction time. Finally, mechanistic studies suggest that the reaction may form the classic Meisenheimer complex through a two-step addition-elimination mechanism.

NOVEL TRIAZINE COMPOUND, AND ORGANIC ELECTRONIC ELEMENT AND PLANT-GROWING LIGHTING THAT USE THE SAME

PROBLEM TO BE SOLVED: To provide a triazine compound which has a high triplet energy level and excellent heat resistance, and can be used as an organic electronic element material realizing an element with high efficiency, low voltage and a long life. SOLUTION: In the triazine compound, as represented by the general formula [1] in the figure, a triazine backbone moiety is linked to a dibenzofuran or dibenzothiophene backbone moiety via a biphenyl backbone moiety, where X is an oxygen atom or sulfur atom. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPO&INPIT