21055-99-2Relevant academic research and scientific papers
Dithioacetal Exchange: A New Reversible Reaction for Dynamic Combinatorial Chemistry
Orrillo, A. Gastón,Escalante, Andrea M.,Furlan, Ricardo L. E.
supporting information, p. 6746 - 6749 (2016/05/11)
Reversibility of dithioacetal bond formation is reported under acidic mild conditions. Its utility for dynamic combinatorial chemistry was explored by combining it with orthogonal disulfide exchange. In such a setup, thiols are positioned at the intersection of both chemistries, constituting a connecting node between temporally separated networks. In reverse: Reversibility of dithioacetal bond formation is reported under acidic mild conditions (see figure). Its utility for dynamic combinatorial chemistry was explored by combining it with orthogonal disulfide exchange. In such a setup, thiols are positioned at the intersection of both chemistries, constituting a connecting node between temporally separated networks.
Graphene oxide (GO)-catalyzed chemoselective thioacetalization of aldehydes under solvent-free conditions
Roy, Babli,Sengupta, Debasish,Basu, Basudeb
supporting information, p. 6596 - 6600 (2015/01/08)
An efficient method for the synthesis of open chain, cyclic, and unsymmetrical dithioacetals from aryl/hetero-aryl/aliphatic aldehydes is described. The reaction is performed using graphene oxide (GO) as the catalyst under solvent-free and aerobic conditions. High chemoselectivity is observed in the reaction as aryl/alkyl ketones do not give thioketals under the condition.
