21086-81-7Relevant articles and documents
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Kohler
, p. 910 (1888)
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MODEL STUDIES FOR INSECT PROTEIN SCLEROTIZATION: OXIDATIVE LOSS OF THE SIDE CHAIN FROM 4-SUBSTITUTED CATECHOLS
Pyne, Stephen G.,Truscott, Roger J. W.,Maxwell, Karin,Morales, M. Carmen,Walsh, Bernadette C.,Wynn, Barbra L.
, p. 661 - 670 (2007/10/02)
The oxidation of several 4-substituted catechols in aqueous solution, pH7 in the presence of aniline results in the formation of 4,5-dianilino-1,2-benzoquinone 2 and the anil of 2 (3).The C-4 substituent is efficiently cleaved and mechanisms are proposed to account for this phenomenon based on HPLC and GC studies and the formation of N-methylaniline when these reactions were performed in the presence of sodium cyanoborohydride.The evidence suggests that the initial step involves the addition of aniline to the catechol C-4 side chain.
Studies on the Synthesis of Azophenines from o-Benzoquinone Dioxime
Paetzold, F.,Niclas, H.-J.,Foerster, H.-J.
, p. 921 - 928 (2007/10/02)
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