21095-90-9Relevant academic research and scientific papers
Metal-free synthesis of aryl ethers in water
Lindstedt, Erik,Ghosh, Raju,Olofsson, Berit
supporting information, p. 6070 - 6073 (2014/01/06)
The first arylation of allylic and benzylic alcohols with diaryliodonium salts is reported. The reaction yields alkyl aryl ethers under mild and metal-free conditions. Phenols are arylated to diaryl ethers in good to excellent yields. The reaction employs diaryliodonium salts and sodium hydroxide in water at low temperature, and excess amounts of the coupling partners are avoided.
Ir(I)-catalyzed enantioselective decarboxylative allylic etherification: A general method for the asymmetric synthesis of aryl allyl ethers
Kim, Dongeun,Reddy, Srinivasa,Singh, Om V.,Lee, Jae Seung,Kong, Suk Bin,Han, Hyunsoo
supporting information, p. 512 - 515 (2013/04/10)
Ir(I)-catalyzed enantioselective decarboxylative allylic etherification of aryl allyl carbonates provides aryl allyl ethers. Key to the generality and high stereoselection of the reaction is the use of the intramolecular decarboxylative allylation process
Regioselective iron-catalyzed decarboxylative allylic etherification
Trivedi, Rushi,Tunge, Jon A.
supporting information; experimental part, p. 5650 - 5652 (2010/02/28)
[Chemical Equation Presented] An anionic iron complex catalyzes the decarboxylative allylation of phenols to form allylic ethers in high yield. The allylation is regioselective rather than regiospecific. This suggests that the allylation proceeds through π-allyl iron intermediates in contrast to related allylations of carbon nucleophiles that have been proposed to proceed via π-allyl complexes. Ultimately, iron catalysts have the potential to replace more expensive palladium catalysts that are typically utilized for decarboxylative couplings.
