21134-16-7Relevant academic research and scientific papers
Electrophilic C-H borylation and related reactions of B-H boron cations
Prokofjevs, Aleksandrs,Jermaks, Janis,Borovika, Alina,Kampf, Jeff W.,Vedejs, Edwin
, p. 6701 - 6711 (2013)
Catalytic procedures are described for the amine-directed borylation of aliphatic and aromatic tertiary amine-boranes. Sequential double borylation is observed in cases where two or more C-H bonds are available that allow 5-center or 6-center intramolecular borylation. The HNTf2-catalyzed borylation of benzylamine-boranes provides a practical means for the synthesis of ortho-substituted arylboronic acid derivatives, suitable for Suzuki-Miyaura cross-coupling applications.
