211811-76-6Relevant academic research and scientific papers
Synthesis of internal acetylenes from vinylic tellurides
Terao, Jun,Kambe, Nobuaki,Sonoda, Noboru
, p. 5511 - 5512 (1998)
Vinylic tellurides were prepared by carbotelluration of acetylenes under light. The subsequent oxidation with sodium hypochlorite followed by pyrolysis gave internal acetylenes in good yields. Combination of these reactions provides a useful method for introduction of alkyl groups to terminal acetylenes.
