Tetrahedron Letters p. 5511 - 5512 (1998)
Update date:2022-07-30
Topics:
Terao, Jun
Kambe, Nobuaki
Sonoda, Noboru
Vinylic tellurides were prepared by carbotelluration of acetylenes under light. The subsequent oxidation with sodium hypochlorite followed by pyrolysis gave internal acetylenes in good yields. Combination of these reactions provides a useful method for introduction of alkyl groups to terminal acetylenes.
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(1998)
