15325-61-8

Basic information

• Product Name: Benzene, [(1E)-3-methyl-1-butenyl]-
• CAS NO: 15325-61-8
• Molecular Formula: C11H14
• Molecular Weight: 146.232
• Mol File: 15325-61-8.mol
• Article Data: 80

Chemical Properties

• CAS DataBase Reference: Benzene, [(1E)-3-methyl-1-butenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1E)-3-methyl-1-butenyl]-(15325-61-8)
• EPA Substance Registry System: Benzene, [(1E)-3-methyl-1-butenyl]-(15325-61-8)

Safety Data

• Hazardous Substances Data: 15325-61-8(Hazardous Substances Data)

Upstream product

• 705-58-8 3-methyl-1-phenyl-2-butanol 
• 1825-62-3 ethyl trimethylsilyl ether 
• 137363-32-7 trans-1-(tert-butyldimethylsilyl)-2,2-dimethyl-4-phenyl-3-isopropyl-1-aza-2-sila-cyclobutane 
• 102-96-5 (2-nitroethenyl)benzene 
• 67219-33-4 2-phenylmethanesulfonyl-benzothiazole 
• 78-84-2 isobutyraldehyde 
• 21960-27-0 Isobutylidene-triphenyl-λ⁵-phosphane 
• 100-52-7 benzaldehyde 
• 74267-40-6 trans-3-isopropyl-2-phenyloxetane 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 75-30-9 2-iodo-propane 
• 5153-67-3 nitrostyrene 
• 78-77-3 Isobutyl bromide 
• 42599-24-6 E-styryl iodide 

Downstream Products

• 4489-84-3 3-methyl-1-phenylbut-2-ene 
• 582-62-7 3-methyl-1-phenylbutan-1-one 
• 2893-05-2 3-methyl-1-phenylbutan-2-one 
• 2439-44-3 3-methyl-2-phenylbutanal 
• 94719-34-3 cis 2-(1-methylethyl)-3-phenyloxirane 
• 94719-35-4 trans 2-(1-methylethyl)-3-phenyloxirane 
• 19776-13-7 (R*,R*)-3-methyl-1-phenyl-1,2-butanediol 
• 127704-36-3 (2,2-Dibromo-3-isopropyl-cyclopropyl)-benzene 
• 769-57-3 α,β,β-trimethylstyrene 
• 53932-93-7 (2S,3S)-2-isopropyl-3-phenylaziridine 
• 420087-35-0 (2R,3R)-2-isopropyl-3-phenylaziridine 
• 15325-56-1 (Z)-3-methyl-1-phenylbut-1-ene 
• 15325-61-8 (E)-(3-methylbut-1-en-1-yl)benzene 
• 141983-65-5 trans-2-methyl-4-phenyl-3-buten-2-amine 

Relevant articles and documents

Kinetic resolution ofN-aryl β-amino alcoholsviaasymmetric aminations of anilines

An efficient kinetic resolution ofN-aryl β-amino alcohols has been developedviaasymmetricpara-aminations of anilines with azodicarboxylates enabled by chiral phosphoric acid catalysis. Broad substrate scope and high kinetic resolution performances were afforded with this method. Control experiments supported the critical roles of the NH and OH group in these reactions.

Visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones

Herein we report a mild, general protocol for visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones. The protocol permits efficient functionalization of sulfones with a broad range of cyclic and acyclic secondary and tert

Enzymatic Primary Amination of Benzylic and Allylic C(sp3)-H Bonds

Aliphatic primary amines are prevalent in natural products, pharmaceuticals, and functional materials. While a plethora of processes are reported for their synthesis, methods that directly install a free amine group into C(sp3)-H bonds remain unprecedented. Here, we report a set of new-to-nature enzymes that catalyze the direct primary amination of C(sp3)-H bonds with excellent chemo-, regio-, and enantioselectivity, using a readily available hydroxylamine derivative as the nitrogen source. Directed evolution of genetically encoded cytochrome P411 enzymes (P450s whose Cys axial ligand to the heme iron has been replaced with Ser) generated variants that selectively functionalize benzylic and allylic C-H bonds, affording a broad scope of enantioenriched primary amines. This biocatalytic process is efficient and selective (up to 3930 TTN and 96percent ee), and can be performed on preparative scale.