211871-01-1

Upstream product

• 51909-56-9 O,O-diethyl N-methylamino(phenyl)methylphosphonate 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 211871-03-3 {[Methyl-(phenyl-trimethylsilanyloxy-methyl)-amino]-phenyl-methyl}-phosphonic acid diethyl ester 
• 211871-06-6 {[(Hydroxy-phenyl-methyl)-methyl-amino]-phenyl-methyl}-phosphonic acid diethyl ester 
• 622-29-7 N-Benzylidenemethylamine 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 211871-04-4 ({[(4-Bromo-phenyl)-trimethylsilanyloxy-methyl]-methyl-amino}-phenyl-methyl)-phosphonic acid diethyl ester 
• 211871-02-2 {[Methyl-(1-methyl-1-trimethylsilanyloxy-ethyl)-amino]-phenyl-methyl}-phosphonic acid diethyl ester 
• 211871-03-3 {[Methyl-(phenyl-trimethylsilanyloxy-methyl)-amino]-phenyl-methyl}-phosphonic acid diethyl ester 

Relevant academic research and scientific papers

Synthesis and Properties of N-Silylated α-Amino Phosphonates

Diethyl α-(N-methyl-N-trimethylsilylamino)benzylphosphonate was prepared by addition of diethyl phosphonate to N-methylbenzalimine, followed by silylation of the resulting amino phosphonate. Reaction of this product with acetone, benzaldehyde, and p-bromobenzaldehyde yields corresponding addition products, siloxy phosphonates, which can be converted to hydroxy phosphonates by methanolysis under mild conditions. Siloxy and hydroxy phosphonates decompose on heating to give the initial methylaminobenzylphosphonate.