21188-84-1

Basic information

• Product Name: N-Anilino-3,4-dihydro-isochinoliniumbromid
• Synonyms: N-Anilino-3,4-dihydro-isochinoliniumbromid
• CAS NO: 21188-84-1
• Molecular Weight: 303.201
• Mol File: 21188-84-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Anilino-3,4-dihydro-isochinoliniumbromid(CAS DataBase Reference)
• NIST Chemistry Reference: N-Anilino-3,4-dihydro-isochinoliniumbromid(21188-84-1)
• EPA Substance Registry System: N-Anilino-3,4-dihydro-isochinoliniumbromid(21188-84-1)

Safety Data

• Hazardous Substances Data: 21188-84-1(Hazardous Substances Data)

Upstream product

• 22901-09-3 2-(2-bromoethyl)benzaldehyde 
• 100-63-0 phenylhydrazine 

Downstream Products

• 21188-82-9 1-(2,6-dimethyl-phenyl)-2-methyl-3-phenyl-1,2,3,5,6,10b-hexahydro-[1,2,4,3]triazaborolo[5,1-a]isoquinoline 
• 21188-80-7 1-butyl-2-methyl-3-phenyl-1,2,3,5,6,10b-hexahydro-[1,2,4,3]triazaborolo[5,1-a]isoquinoline 
• 106599-66-0 1,3-diphenyl-1,10b-dihydro-[1,2,4]triazolo[5,1-a]isoquinoline-2-thione 
• 5825-72-9 1,3-diphenyl-1,10b-dihydro-[1,2,4]triazolo[5,1-a]isoquinolin-2-one 

Relevant articles and documents

Isoquinolinium N-arylimides and some cycloadditions to heterocumulenes

The red isoquinolinium N-arylimides 19-23 are azomethine imines of which the C=N bond is part of an aromatic ring. The N-(4-nitrophenyl)imide 22 and the N-(2-pyridyl)imide 23 were obtained crystalline; in solution the latter equilibrates with the hexahydrotetrazine 24 as its dimer. The N-phenyl-imide 19 is not stable; an isolated solid appears to be a tetramer. Generated by deprotonation of 11-13, the N-arylimides 19-21 undergo in situ cycloadditions to carbon disulfide, phenyl isocyanate, phenyl isothiocyanate, and diphenylketene. The storable CS2 adduct 29 offers a neutral source of the N-phenylimide 19, since a cycloreversion equilibrium is established in solution.