212890-82-9

Upstream product

• 3282-30-2 pivaloyl chloride 
• 627503-57-5 (S)-3,3-Dibenzyl-5-[(diphenylphosphanyl)-methyl]-pyrrolidin-2-one 
• 212890-92-1 (S)-(-)-tert-butyl 4,4-bisbenzyl-2-[((4-methylphenyl)sulfonyloxy)methyl]pyrrolidinecarboxylate 
• 212890-91-0 (S)-(-)-tert-butyl 4,4-bisbenzyl-2-(hydroxymethyl)pyrrolidinecarboxylate 
• 212890-90-9 (S)-(+)-(4,4-dibenzylpyrrolidin-2-yl)methan-1-ol 
• 100-39-0 benzyl bromide 
• 212890-88-5 (S)-(+)-1-aza-3,3-bisbenzyl-8,8-dimethyl-7-oxabicyclo[3.3.0]octan-2-one 
• 212890-89-6 (S)-(+)-3,3-bisbenzyl-5-(hydroxymethyl)pyrrolidin-2-one 
• 99208-71-6 (5S)-1-aza-2,2-dimethyl-3-oxa-8-oxo-bicyclo[3.3.0]octane 
• 212890-93-2 (S)-(-)-tert-butyl 4,4-bisbenzyl-2-[(diphenylphosphino)methyl]pyrrolidinecarboxylate 

Downstream Products

• 457622-82-1 C₈H₁₂Rh(P(C₆H₅)2CH₂CHCH₂C(CH₂C₆H₅)2CH₂NC(O)C(CH₃)3)⁽¹⁺⁾*SbF₆^(1-)=C₈H₁₂Rh(P(C₆H₅)2CH₂CHCH₂C(CH₂C₆H₅)2CH₂NC(O)C(CH₃)3)SbF₆ 

Relevant academic research and scientific papers

Asymmetric Alkylation of N-Toluenesulfonylimines with Dialkylzinc Reagents Catalyzed by Copper-Chiral Amidophosphine

The synthetic procedure of a chiral amidophosphine ligand 5 bearing two bulky substituents, 2,4,6-trimethylphenylmethyl or 2,4,6-triisopropylphenylmethyl groups, on the pyrrolidine ring was improved by employing the borane-THF reduction of the lactam-alco

An external chiral amidophosphine ligand for asymmetric conjugate addition of organocopper

Two types of external, chiral amidophosphine ligands, 1-5, were prepared. Examination of their behavior in an asymmetric conjugate addition reaction of organocuprate revealed the possibility for steric tuning to realize high selectivity.