21299-27-4Relevant articles and documents
1,3-Diaxial steric effects and intramolecular hydrogen bonding in the conformational equilibria of new cis-1,3-disubstituted cyclohexanes using low temperature NMR spectra and theoretical calculations
De Oliveira, Paulo R.,Rittner, Roberto
, p. 30 - 37 (2005)
The conformational equilibria of 3-X-cyclohexanol [X = F (1), Cl (2), Br (3), I (4), Me (5), NMe2 (6) and MeO (7)] and of 3-X- methoxycyclohexane [X = F (8), Cl (9), Br (10), I (11), Me (12), NMe2 (13) and MeO (14)] cis isomers were
Method for preparing alicyclic ketone by catalytic oxidation of alicyclic alcohol compound
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Paragraph 0029; 0030, (2016/12/01)
The invention provides a method for preparing alicyclic ketone by catalytic oxidation of an alicyclic alcohol compound. The method takes air or oxygen as an oxidant and uses a catalyst system consisting two components of aza-adamantane free radical of nitroxide and a vanadium oxygen compound, and the alicyclic alcohol compound is oxidated into the corresponding alicyclic ketone with high selectivity at 50 to 120 DEG C. Compared with 2,2,6,6,-tetramethyl piperidine free radical of nitroxide, the aza-adamantane free radical of nitroxide has smaller influence of steric hindrance in a catalytic oxidation secondary alcohol reaction, and the catalyst system consisting of the vanadium oxygen compound has higher alicyclic alcohol oxidating efficiency. Compared with the conventional stoichiometric chemistry oxidation methods such as manganese dioxide, chromium trioxide and sodium hypochlorite, the method provided by the invention has the characteristics of few side products, mild reaction conditions, small environmental pollution and the like, and has very high practicability and economical efficiency.
A SIMPLE AND CONVENIENT SYNTHESIS OF β-HALOKETONES.
Marx, John N.
, p. 1529 - 1532 (2007/10/02)
A new rapid quantitative method to synthesize β-halo-ketones is described (eqn 2) wich utilizes the reaction of an enone with a tetraalkyl ammonium halide in anhydrous trifluoro acetic acid.The method is especially convenient for the preparation of β-iodoketones.