213122-60-2

Upstream product

• 90132-06-2 5-oxo-7-trimethylsilylhept-6-ynoic acid methyl ester 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 213122-62-4 (E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-hexa-1,4-dien-3-ol 
• 157944-64-4 (S)-5-Methoxymethoxy-7-trimethylsilanyl-hept-6-ynoic acid methyl ester 
• 213122-61-3 ((S)-7,7-Dimethoxy-3-methoxymethoxy-hept-1-ynyl)-trimethyl-silane 
• 213122-69-1 (S)-5-Methoxymethoxy-7-trimethylsilanyl-hept-6-ynal 
• 157944-65-5 (6E,8Z)-(S)-14,14-Dimethoxy-10-methoxymethoxy-8-trimethylsilanyl-tetradeca-6,8-dienal 
• 213122-70-4 (6E,8Z)-(S)-14,14-Dimethoxy-10-methoxymethoxy-8-trimethylsilanyl-tetradeca-6,8-dien-1-ol 
• 158059-77-9 ((E)-(S)-1-Iodo-7,7-dimethoxy-3-methoxymethoxy-hept-1-enyl)-trimethyl-silane 
• 120085-71-4 (S)-5-hydroxy-7-trimethylsilylhept-6-ynoic acid methyl ester 
• 146983-30-4 4-{[(tert-butyldiphenylsilyl)oxy]methyl}-2(E),4(Z)-hexadienol 
• 129144-88-3 2-{[(tert-butyldiphenylsilyl)oxy]methyl}-2(E)-butenal 
• 1501-26-4 methyl 4-(chlorocarbonyl)butyrate 
• 157944-68-8 2-(diethoxyphosphoryl)propionic acid allyl ester 

Downstream Products

• 157944-70-2 (1R,2R,4aS,5S,8aR)-2-[(5E,7E,9E)-9-(tert-Butyl-diphenyl-silanyloxymethyl)-undeca-5,7,9-trienyl]-5-methoxymethoxy-1-methyl-4-trimethylsilanyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid allyl ester 
• 157944-69-9 C₅₆H₈₂O₈Si₂ 

Relevant academic research and scientific papers

Enantioselective total synthesis of (-)-chlorothricolide via the tandem inter- and intramolecular Diels-Alder reaction of a hexaenoate intermediate

An enantioselective total synthesis of (-)-chlorothricolide (1) has been completed via a route involving the tandem inter- and intramolecular Dieis-Alder (IMDA) reaction of hexaenoate 19 and the chiral dienophile (R)-12. This reaction, which establishes s