21720-68-3Relevant academic research and scientific papers
Regiodivergent Aromatic Electrophilic Substitution Using Nitrosoarenes in Hexafluoroisopropanol: A Gateway for Diarylamines and p-Iminoquinones Synthesis
Pradhan, Suman,Roy, Sourav,Ghosh, Soumen,Chatterjee, Indranil
supporting information, p. 4294 - 4301 (2019/08/20)
A metal-free aromatic electrophilic substitution reaction using nitrosoarenes as the electrophile in 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) is reported. HFIP activates nitrosoarene towards the electrophilic C?H amination followed by a concomitant N?O bo
Oximation of 2-(R1-Amino)-4-(R2-imino)naphthalen-1(4H)-ones
Gornostaev,Rukovets,Arnold,Khalyavina, Yu. G.,Gatilov, Yu. V.
, p. 78 - 86 (2018/06/15)
The oximation of 2-(R1-amino)-4-(R2-imino)naphthalen-1(4H)-ones with hydroxylamine hydrochloride in pyridine afforded 2-(R-amino)-4-(hydroxyimino)naphthalen-1(4H)-ones.
RESEARCH IN THE CHEMISTRY OF HETEROCYCLIC QUINONE IMINES. 11. EFFECT OF BENZANNELATION ON THE OXIDATIVE CYCLIZATION OF DIARYLAMINO-N-ARYL-1,4-BENZOQUINONE MONOIMINES TO PHENAZINONE DERIVATIVES
Afanas'eva, G. B.,Tsoi, E. V.
, p. 616 - 620 (2007/10/02)
2,5-Diarylamino-N-α(β)-naphthyl-1,4-benzoquinone monoimines undergo oxidative cyclization to give benzannelated phenazinone derivatives.The effect of an N-aryl fragment on the ease of cyclization decreases in the order N-β-naphthyl > N-α-naphthyl > N-phenyl. 2-Arylamino-N-phenyl-1,4-naphthoquinone monoimines do not undergo oxidative cyclization to phenazinones.
Nitroxide Radicals. Part 21. Spontaneous Decomposition of N-Aryl 1- and 2-Naphthyl Nitroxides
Forrester, Alexander R.,Fullerton, Joseph D.,McConnachie, Gordon
, p. 1759 - 1764 (2007/10/02)
N-Aryl 1-naphthyl nitroxides self-react in solution to give the corresponding secondary amines and N-aryl-1,4-naphthoquinone imines.When reaction at the 4-naphthyl position is hindered by substituents benzoquinone imines are also produced.N-Phenyl 2-naphthyl nitroxide under similar conditions gives the corresponding amine and 2-phenylamino-1,4-naphthoquinone via a 1,2-naphthoquinone imine N-oxide intermediate.
Reactivity and Structure of N-Phenyl-1-naphthylamines and Related Compounds. Part 3. Reaction with Oxygen-centred Radicals
Forrester, Alexander R.,Fullerton, Joseph D.,McConnachie, Gordon
, p. 2711 - 2715 (2007/10/02)
Comparison is made between products obtained by oxidation of N-phenyl-1-naphthylamines and 1-naphthyl phenyl nitroxides with peroxyl radicals.It is concluded that oxidation of the amines does not proceed to a considerable extent via the nitroxides.Comparison is also made of products obtained from these amines and nitroxides by oxidation with Fremy's salt.
