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2174-58-5

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2174-58-5 Usage

Chemical Properties

White solid

Check Digit Verification of cas no

The CAS Registry Mumber 2174-58-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,7 and 4 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 2174-58:
(6*2)+(5*1)+(4*7)+(3*4)+(2*5)+(1*8)=75
75 % 10 = 5
So 2174-58-5 is a valid CAS Registry Number.
InChI:InChI=1/C5H8O4/c1-3(5(8)9)2-4(6)7/h3H,2H2,1H3,(H,6,7)(H,8,9)/t3-/m0/s1

2174-58-5 Well-known Company Product Price

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  • TCI America

  • (M1227)  (S)-(-)-Methylsuccinic Acid  >98.0%(GC)(T)

  • 2174-58-5

  • 5g

  • 880.00CNY

  • Detail

2174-58-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name (2S)-2-methylbutanedioic acid

1.2 Other means of identification

Product number -
Other names (S)-2-Methylsuccinic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2174-58-5 SDS

2174-58-5Relevant articles and documents

THE TOTAL SYNTHESIS OF PIPTOSIDIN

Poss, A. J.,Smyth, M. S.

, p. 5469 - 5472 (1987)

The synthesis of piptosidin, 2a, by the Michael addition of ascorbic acid to tigloyl cyanide is reported.

Rapid and Efficient Isolation of the Nicotinic Receptor Antagonist Methyllycaconitine from Delphinium: Assignment of the Methylsuccinimide Absolute Stereochemistry as S

Coates, Philippa A.,Blagbrough, Ian S.,Hardick, David J.,Rowan, Michael G.,Wonnacott, Susan,Potter, Barry V. L.

, p. 8701 - 8704 (1994)

Methyllycaconitine (MLA) has been isolated from Garden Hybrid Delphinium and purified by vacuum liquid chromatography. 13C NMR and optical rotation has been used to characterize the absolute configuration of the methylsuccinimide moiety as S.Ligand binding assays confirmed the potency of MLA and its selectivity for α-bungarotoxin-sensitive neuronal nicotinic acetylcholine receptors.

Preparation of Both Enantiomers of Malic and Citramalic Acid and Other Hydroxysuccinic Acid Derivatives by Stereospecific Hydrations of cis or trans 2-Butene-1,4-dioic Acids with Resting Cells of Clostridium formicoaceticum

Eck, Richard,Simon, Helmut

, p. 13641 - 13654 (1994)

(R)-Malic, (S)-malic, (R)-citramalic, (S)-citramalic, (2R,3S)-2-hydroxy-3-methylsuccinic and (2R,3S)-2,3-dimethyl-2-hydroxysuccinic acid were prepared on scales up to 25 mmol by stereospecific addition of water to different 2-butene-1,4-dioic acid derivatives catalyzed by resting cells of Clostridium formicoaceticum (Scheme 1).The (3R)-monodeuterio (R)- and (S)-malic acid as well as (R)- and (S)-citramalic acid were prepared using freeze-dried cells in 2H2O-buffer.The stereochemical purity of the products was in most cases >/= 99percent.

Enantiospecific C-H Activation Using Ruthenium Nanocatalysts

Taglang, Céline,Martínez-Prieto, Luis Miguel,Del Rosal, Iker,Maron, Laurent,Poteau, Romuald,Philippot, Karine,Chaudret, Bruno,Perato, Serge,Sam Lone, Ana?s,Puente, Céline,Dugave, Christophe,Rousseau, Bernard,Pieters, Grégory

supporting information, p. 10474 - 10477 (2015/09/02)

The activation of C-H bonds has revolutionized modern synthetic chemistry. However, no general strategy for enantiospecific C-H activation has been developed to date. We herein report an enantiospecific C-H activation reaction followed by deuterium incorporation at stereogenic centers. Mechanistic studies suggest that the selectivity for the α-position of the directing heteroatom results from a four-membered dimetallacycle as the key intermediate. This work paves the way to novel molecular chemistry on nanoparticles.

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