218445-42-2Relevant academic research and scientific papers
Platinum-catalyzed ring opening of 1,2-cyclopropanated sugars with O-nucleophiles. Convenient synthesis of 2-C-branched carbohydrates
Beyer,Skaanderup,Madsen
, p. 9575 - 9583 (2000)
A new reaction is described catalyzed by Zeise's dimer that allows for ring opening of 1,2-cyclopropanated sugars with O-nucleophiles to give 2-C-branched carbohydrates. A number of O-nucleophiles can participate in the ring opening including alcohols, ph
New stable anomeric hydroperoxides derived from 2-deoxysugars; Enantioselective epoxidation of 2-methyl-1,4-naphthoquinone
Kosnik, Wioletta,Stachulski, Andrew V.,Chmielewski, Marek
, p. 1975 - 1981 (2007/10/03)
3,5-Di- or 3,4,6-tri-O-substituted-2-deoxysugars or their glycosides can be oxidized with hydrogen peroxide in the presence of an acid catalyst to the corresponding anomeric hydroperoxides, which are relatively stable, can be separated into pure anomers b
