21860-48-0

Basic information

• Product Name: (E)-1-phenyl-3-tosylprop-2-en-1-one
• Synonyms: (E)-1-phenyl-3-tosylprop-2-en-1-one
• CAS NO: 21860-48-0
• Molecular Weight: 286.351
• Mol File: 21860-48-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-phenyl-3-tosylprop-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenyl-3-tosylprop-2-en-1-one(21860-48-0)
• EPA Substance Registry System: (E)-1-phenyl-3-tosylprop-2-en-1-one(21860-48-0)

Safety Data

• Hazardous Substances Data: 21860-48-0(Hazardous Substances Data)

Upstream product

• 100786-76-3 2-bromo-1-phenyl-3-(toluene-4-sulfonyl)-propan-1-one 
• 936-59-4 3-chloropropiophenone 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 52481-46-6 1-phenyl-3-tosylpropan-1-one 
• 98-88-4 benzoyl chloride 
• 536-57-2 p-toluene sulfinic acid 
• 3623-15-2 phenyl propargyl ketone 
• 15724-86-4 E-2-chlorovinyl phenyl ketone 

Downstream Products

• 19854-92-3 phenyl-(1⁽²⁾H-pyrazol-3-yl)-methanone 
• 2458-26-6 3-phenylpyrazole 
• 337308-27-7 3-phenyl-5-(toluene-4-sulfonyl)-4,5-dihydro-1H-pyrazole 
• 92525-20-7 (1-methyl-1H-pyrazol-3-yl)(phenyl)methanone 

Relevant articles and documents

Silver(I)-Promoted Radical Sulfonylation of Allyl/Propargyl Alcohols: Efficient Synthesis of γ-Keto Sulfones

An efficient Ag2CO3-promoted sulfonylation of allyl/propargyl alcohols with sodium sulfinates has been developed. The reaction tolerates a wide range of functional groups to deliver γ-keto sulfones in high yields (up to 93 %). Propargyl alcohols furnished trimerization product 1,3,5-triaroylbenzenes in the presence of sodium methanesulfinate under the standard conditions. A mechanism involving a sulfonyl radical was suggested.