219951-10-7

Upstream product

• 930-69-8 sodium thiophenolate 
• 591-51-5 phenyllithium 
• 394-52-5 pentafluoroethyl phenyl ketone 
• 137504-63-3 2,2,3,3,3-pentafluoro-1,1-bis(phenylthio)propylbenzene 
• 1979-51-7 1,1,3,3,3-pentafluoro-2-phenylpropene 
• 219951-09-4 β-CF3-α,β-diphenylvinyl sulfide 

Downstream Products

• 36029-59-1 3,3,3-Trifluoro-1,1,2-triphenylpropene 
• 36029-62-6 1-(Trifluormethyl)-2-(p-fluorphenyl)-1,2-diphenylethylen 
• 34288-92-1 (Z)-1-(4-methoxyphenyl)-1,2-diphenyl-3,3,3-trifluoropropene 
• 36029-60-4 (E)-3,3,3-trifluoro-1-(4-methoxyphenyl)-1,2-diphenylpropene 
• 182279-48-7 1-Chloro-4-((E)-3,3,3-trifluoro-1,2-diphenyl-propenyl)-benzene 

Relevant academic research and scientific papers

A highly stereoselective preparation of CF3-substituted 1-aryl-1,2-diphenylethenes: Application to the synthesis of panomifene

β-CF3-α,β-diphenylvinyl sulfide 3a was prepared stereoselectively in 77% yield from the reaction of 2 with phenyllithium at room temperature for 5 h. Oxidation of 3a with MCPBA afforded the corresponding vinyl sulfone 4a, in which (E)-4a can be

Preparation of α- or β-trifluoromethylated vinylstannanes and their cross-coupling reactions

α - or β-Trifluoromethylated vinylstannanes 1, 2a, 3 and 4 were prepared form 1,1-bis(phenylthio)-2,2,3,3,3-pentafluoropropylbenzene (5) via several steps. The cross-coupling arylation reactions of 1-4 with aryl iodides bearing a bromo, methoxy, methyl, n

A new method for the preparation of perfluoroalkylated triphenylethylene derivatives

The reaction of perfluoroalkylated dithioketals 1 with 2.1 equiv. of phenyllithium afforded the corresponding vinyl sulfides 2 in good yields. Treatment of vinyl sulfones 3, obtained from the oxidation of 2, with phenyllithium derivatives resulted in the