220437-87-6Relevant academic research and scientific papers
Oxidation and rearrangement of 5-substituted 5- ethoxycarbonyl[1,2,4]triazolidine-3-thiones
Schantl, Joachim G.,Lang, Sergius,Wurst, Klaus
, p. 251 - 258 (2007/10/03)
The reaction of ethyl 2-(phenylhydrazono)alkanoates (1) with potassium thiocyanate in acetic acid affords 5-ethoxycarbonyl-substituted [1,2,4]triazolidine-3-thiones (3). Oxidation (KMnO4) converts 3 into 1- ethoxycarbonyl-2,3-dihydro-1H-[1,2,4]
