220586-16-3Relevant academic research and scientific papers
Nanoceria as a recyclable catalyst/support for the cyanosilylation of ketones and alcohol oxidation in cascade
Garnes-Portolés, Francisco,Leyva-Pérez, Antonio,Rivero-Crespo, Miguel ángel
, p. 21 - 28 (2020)
The cyanosilylation of carbonyl compounds is a fundamental reaction in organic synthesis, to give cyanohydrins. Ketones are particularly reluctant to cyanosilane addition and require the action of a catalyst, and despite many soluble Br?nsted and Lewis ac
Three N-H functionalized metal-organic frameworks with selective CO 2 uptake, dye capture, and catalysis
Zhu, Yu,Wang, Yan-Mei,Zhao, Sheng-Yun,Liu, Pan,Wei, Chao,Wu, Yun-Long,Xia, Chang-Kun,Xie, Ji-Min
, p. 7692 - 7699 (2014)
Three N-H functionalized metal-organic frameworks, Pb-DDQ, Zn-DDQ, and Cu-DDQ, were synthesized with a new flexible dicarboxylate ligand based on quinoxaline (H2DDQ = N,N′-dibenzoic acid-2,3- diaminoquinoxaline). CO2 adsorptions indi
Two chelating-amino-functionalized lanthanide metal-organic frameworks for adsorption and catalysis
Zhu, Yu,Wang, Yanmei,Liu, Pan,Xia, Changkun,Wu, Yunlong,Lu, Xiaoqing,Xie, Jimin
, p. 1955 - 1961 (2015)
Two chelating-amino-functionalized lanthanide metal-organic frameworks, Er-DADQ and Eu-DADQ, were synthesized with a flexible dicarboxylate ligand based on quinoxaline (H2DADQ = N,N′-dibenzoic acid-2,3-diaminoquinoxaline). N2 adsorpt
Conjugated Bis-Guanidines (CBGs) as β-Diketimine Analogues: Synthesis, Characterization of CBGs/Their Lithium Salts and CBG Li Catalyzed Addition of B?H and TMSCN to Carbonyls
Peddarao, Thota,Baishya, Ashim,Sarkar, Nabin,Acharya, Rudresh,Nembenna, Sharanappa
, p. 2034 - 2046 (2021/05/27)
Herein, we report a range of conjugated bis-guanidines (CBGs) L [L={(ArHN)(ArHN)C=N?C=(NAr)(NHAr)}; Ar=2, 6-Me2 - C6H3, (1), 2, 4, 6-Me3?C6H2, (2), 2, 6-Et2?C6H3
Ultrathin Near-Infrared Light Activated Nano-Hotplate Catalyst
Wu, Xiangyang,Yeow, Edwin K. L.
, (2020/09/09)
A combined photothermal-catalytic system that contains a single active element, without using different entities for separate roles (catalytic vs photothermal), is designed here for efficient catalytic reactions. Herein, ultrathin (sub-6 nm) rectangular-l
NOVEL LXR MODULATORS WITH BICYCLIC CORE MOIETY
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Page/Page column 58-59, (2020/01/24)
The present invention relates to bicyclic compounds (e.g. indoles) containing a sulfonyl moiety, which bind to the liver X receptor (LXRα and/or LΧΚβ) and act preferably as inverse agonists of LXR.
Cyanosilylation reaction method using hydroboron to catalyze ketone
-
Paragraph 0029, (2018/05/03)
The invention relates to the field of organic chemistry, aiming at solving the problems that the existing ketone-catalyzing cyanosilylation reaction has the defects of complicated catalyst structure,high preparation cost and more application limitations,
Syntheses, Structures, and Catalytic Activities of the Anionic Heterobimetallic Rare-Earth Metal Complexes Supported by Pyrrolyl-Substituted 1,2-Diimino Ligands
Wang, Wei,Wang, Xiaojia,Zhou, Shuangliu,Xu, Xiaolong,Du, Jun,Zhang, Lijun,Mu, Xiaolong,Wei, Yun,Zhu, Xiancui,Wang, Shaowu
supporting information, p. 10390 - 10400 (2018/08/28)
A series of the anionic heterobimetallic rare-earth metal complexes supported by trans- or chiral pyrrolyl-substituted 1,2-diimino ligands were synthesized in good yields via reactions of [(Me3Si)2N]3RE(μ-Cl)Li(THF)3
Beyond Hydrofunctionalisation: A Well-Defined Calcium Compound Catalysed Mild and Efficient Carbonyl Cyanosilylation
Yadav, Sandeep,Dixit, Ruchi,Vanka, Kumar,Sen, Sakya S.
supporting information, p. 1269 - 1273 (2018/02/06)
Organocalcium compounds have been reported as efficient catalysts for various transformations, for cases in which one of the substrates contained an E?H (E=B, N, Si, P) bond. Here, we look at the possibility of employing an organocalcium compound for a tr
Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones
Bisai, Milan Kumar,Das, Tamal,Vanka, Kumar,Sen, Sakya S.
supporting information, p. 6843 - 6846 (2018/06/26)
Simple and readily accessible lithium compounds such as 2,6-di-tert-butyl phenolate lithium (1a), 1,1′ dilithioferrocene (1b) and nacnac lithium (1c) are found to be efficient single site catalysts for hydroboration of a range of aldehydes and ketones wit
