220662-68-0

Basic information

• Product Name: 2-{[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy]methyl}benzoic acid
• Synonyms: 2-{[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy]methyl}benzoic acid
• CAS NO: 220662-68-0
• Molecular Weight: 674.791
• Mol File: 220662-68-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-{[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy]methyl}benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy]methyl}benzoic acid(220662-68-0)
• EPA Substance Registry System: 2-{[(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy]methyl}benzoic acid(220662-68-0)

Safety Data

• Hazardous Substances Data: 220662-68-0(Hazardous Substances Data)

Upstream product

• 220662-78-2 Acetic acid (2R,3R,4S,5S,6S)-3,5-diacetoxy-2-acetoxymethyl-6-(2-bromo-benzyloxy)-tetrahydro-pyran-4-yl ester 
• 100-39-0 benzyl bromide 
• 635320-28-4 2-((2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-benzoic acid benzyl ester 
• 124-38-9 carbon dioxide 
• 220662-67-9 2-bromobenzyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranoside 
• 121238-27-5 2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl trichloroimidate 
• 18982-54-2 o-bromobenzyl alcohol 
• 365534-59-4 2'-(benzyloxycarbonyl)benzyl α-D-mannopyranoside 

Downstream Products

• 220662-79-3 2-((2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-benzoic acid (2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethyl ester 
• 220662-82-8 2-((2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-benzoic acid (2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 78153-79-4 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl fluoride 
• 220662-69-1 methyl 6-{1-[2-(((2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy)methyl)phen-1-yl]vinyl}-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 220662-70-4 methyl 4-{1-[2-(((2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)oxy)methyl)phen-1-yl]vinyl}-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 55094-26-3 methyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1→6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 82659-59-4 3-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)propene 
• 82659-61-8 3-(2',3',4',6'-tetra-O-benzyl-β-D-mannopyranosyl)-1-propene 
• 38184-10-0 phenyl 2,3,4,6-tetra-O-benzyl-1-thio-α-D-mannopyranoside 
• 64694-18-4 methyl 4-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)(1→4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

2′-Carboxybenzyl glycosides: glycosyl donors for C-glycosylation and conversion into other glycosyl donors

Glycosylation of various glycosyl acceptors with 2′-carboxybenzyl (CB) 2,3,4,6-tetra-O-benzyl-β-d-glucopyranoside and CB 2,3,4,6-tetra-O-benzyl-α-d-mannopyranoside as glycosyl donors afforded α-C-glycosides exclusively or predominantly in good yields. CB

Glycosylation reactions with a (4-alkoxypentadienyl)oxy leaving group linking the glycosyl donor and the acceptor moiety

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