221216-93-9

Upstream product

• 19790-60-4 3-Benzyloxypropanal 
• 58059-08-8 tert-butyl (R)-p-toluenesulfinylacetate 

Downstream Products

• 221217-00-1 (2R,6R)-6-(2-Benzyloxy-ethyl)-2-tert-butyl-[1,3]dioxan-4-one 
• 221217-37-4 Acetic acid (2R,6R)-6-(2-benzyloxy-ethyl)-2-methyl-[1,3]dioxan-4-yl ester 
• 221217-07-8 Acetic acid (2R,6R)-6-(2-benzyloxy-ethyl)-2-tert-butyl-[1,3]dioxan-4-yl ester 
• 221217-51-2 {2-[(2S,4R,6R)-6-(2-Benzyloxy-ethyl)-2-methyl-[1,3]dioxan-4-ylmethyl]-allyl}-trimethyl-silane 
• 221217-56-7 C₂₇H₄₁IO₅ 
• 221217-80-7 2-[(2R,4S,6R)-6-(2-Benzyloxy-ethyl)-2-methyl-[1,3]dioxan-4-ylmethyl]-3-((2R,4R,6R)-2-tert-butyl-6-iodomethyl-[1,3]dioxan-4-yl)-propane-1,2-diol 
• 591251-75-1 (R)-5-(benzyloxy)-3-hydroxypentanoic acid 

Relevant academic research and scientific papers

Asymmetric synthesis of β-hydroxyesters by aldol type condensation of enantiomerically pure t-butyl p-tolyl sulfinyl acetate: Unexpected substituent effect on the absolute configuration of the product

Aldol type condensation of enantiomerically pure t-butyl p-tolyl sulfinyl acetate was shown to give the opposite configuration at the hydroxylic center in the case of an α,β-unsaturated aldehyde, a result which is in sharp contrast with literature results. The absolute configurations of the aldol products were determined by X-ray crystallography.