58059-08-8

Basic information

• Product Name: Acetic acid, [(4-methylphenyl)sulfinyl]-, 1,1-dimethylethyl ester, (R)-
• CAS NO: 58059-08-8
• Molecular Formula: C13H18O3S
• Molecular Weight: 254.35
• Mol File: 58059-08-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(4-methylphenyl)sulfinyl]-, 1,1-dimethylethyl ester, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(4-methylphenyl)sulfinyl]-, 1,1-dimethylethyl ester, (R)-(58059-08-8)
• EPA Substance Registry System: Acetic acid, [(4-methylphenyl)sulfinyl]-, 1,1-dimethylethyl ester, (R)-(58059-08-8)

Safety Data

• Hazardous Substances Data: 58059-08-8(Hazardous Substances Data)

Upstream product

• 540-88-5 acetic acid tert-butyl ester 
• 1517-82-4 (-)S sulfinate de menthyle 
• 5292-43-3 bromoacetic acid tert-butyl ester 
• 190448-84-1 (1S,5R,7R)-10,10-Dimethyl-4-((R)-toluene-4-sulfinyl)-3-thia-4-aza-tricyclo[5.2.1.0^1,5]decane 3,3-dioxide 
• 50444-99-0 (1R,2S,5R)-menthyl-(S)-p-toluenesulfinate 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 36304-27-5 tert-butyl 1-(p-tolylthio)acetate 
• 142635-27-6 (4R,5S)-4-methyl-5-phenyl-3-<(R)-p-tolylsulfinyl>-2-isoxazolidinone 

Downstream Products

• 56618-58-7 methyl (R)-3-hydroxydecanoate 
• 75369-69-6 (R)-2-Hydroxy-2-methyl-3-((R)-toluene-4-sulfinyl)-succinic acid 4-tert-butyl ester 1-ethyl ester 
• 79816-64-1 tert-butyl α-(p-tolylsulfinyl)-β-hydroxymyristate 
• 133760-93-7 (E)-(S)_s-3-t-butoxycarbonyl-3-p-tolylsulfinylpropenoic acid 
• 1022349-67-2 C₂₃H₃₀O₅S 
• 1022349-66-1 C₂₃H₃₀O₅S 
• 1611465-74-7 C₁₆H₂₄O₄S 
• 36615-45-9 methyl (S)-3-hydroxy-3-phenylpropionate 
• 133760-96-0 (1R,2S,3R,4S)-2-(Toluene-4-sulfinyl)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid 2-tert-butyl ester 3-methyl ester 
• 133760-96-0 (1S,2S,3R,4R)-2-(Toluene-4-sulfinyl)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid 2-tert-butyl ester 3-methyl ester 

Relevant articles and documents

ION PAIR CATALYSIS OF TUNGSTATE AND MOLYBDATE

D The present invention relates to ion pair catalysts (I) comprising the cationic bisguanidinium ligand (A) and diperoxomolybdate anion (B). The present invention also relates to ion pair catalysts (III) comprising the cationic bisguanidinium ligand (C) and peroxotungstate anion (D). It further relates to the use of the said catalysts in the manufacture of enantiomerically enriched sulfoxides.

Diastereofacial selectivity in aldol-type condensation induced by optically pure α-sulfinyl acetate with α-substituted aldehydes

Highly diastereoselective aldol-type condensations induced by the chiral magnesium enolate of tert-butyl p-tolyl sulfinyl acetate were performed with optically pure alkyl or hydroxy α-substituted aldehydes. The addition of chiral α-sulfinyl acetate to var

3. Naphthopyranquinone Antibiotics: Novel Enantioselective Syntheses of Frenolicin B and Some of Its Stereoisomers

Two new enantioselective syntheses of the naphthopyranquinone antibiotic frenolicin B (1), of its enantiomer 2, and of its diastereoisomers 3 and 4 were accomplished using two different routes from optically active β-hydroxy esters (R)- and (S)-11 and 18.