Tetrahedron Letters p. 2923 - 2925 (2001)
Update date:2022-07-31
Topics:
Solladié, Guy
Bauder, Claude
Arce-Dubois, Eva
Pasturel-Jacopé, Yacine
Aldol type condensation of enantiomerically pure t-butyl p-tolyl sulfinyl acetate was shown to give the opposite configuration at the hydroxylic center in the case of an α,β-unsaturated aldehyde, a result which is in sharp contrast with literature results. The absolute configurations of the aldol products were determined by X-ray crystallography.
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