22236-47-1

Basic information

• Product Name: Benzenesulfonamide, N-1,4-dioxan-2-yl-4-methyl-
• Synonyms: 1,4-dioxacyclohexan-2-yl-tolylsulfonamide;Benzenesulfonamide,N-1,4-dioxan-2-yl-4-methyl
• CAS NO: 22236-47-1
• Molecular Formula: C11H15NO4S
• Molecular Weight: 257.31
• Mol File: 22236-47-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-1,4-dioxan-2-yl-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-1,4-dioxan-2-yl-4-methyl-(22236-47-1)
• EPA Substance Registry System: Benzenesulfonamide, N-1,4-dioxan-2-yl-4-methyl-(22236-47-1)

Safety Data

• Hazardous Substances Data: 22236-47-1(Hazardous Substances Data)

Upstream product

• 123-91-1 1,4-dioxane 
• 70-55-3 toluene-4-sulfonamide 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 21849-40-1 dibromamine-T 
• 41085-71-6 bromamine T 
• 127-65-1 chloroamine-T 
• 110-87-2 3,4-dihydro-2H-pyran 

Downstream Products

• 783-88-0 N-<2-(2-hydroxyethoxy)ethyl>-4-methylbenzenesulfonamide 

Relevant articles and documents

Amination of ethers using chloramine-T hydrate and a copper(I) catalyst

Amination of C-H bonds activated by ether oxygen atoms is facile with chloramine-T as nitrene source and copper(I) chloride in acetonitrile as catalyst. For cyclic ethers the hemiaminal products are generally stable and can be isolated pure. For acyclic e

Heterogeneous copper-based catalysts for the amidation of activated CH bonds

Copper species highly dispersed on suitable inert oxide supports catalyze the amidation of the α-CH bond of cyclic ethers using a commercial, environmentally benign nitrene source such as chloramine T. The catalytic efficiency depends on the nature of the

A Metal–Organic Framework with Exceptional Activity for C?H Bond Amination

The development of catalysts capable of fast, robust C?H bond amination under mild conditions is an unrealized goal despite substantial progress in the field of C?H activation in recent years. A Mn-based metal–organic framework (CPF-5) is described that promotes the direct amination of C?H bonds with exceptional activity. CPF-5 is capable of functionalizing C?H bonds in an intermolecular fashion with unrivaled catalytic stability producing >105 turnovers.

Iron-catalyzed efficient intermolecular amination of C(sp3)-H bonds with bromamine-T as nitrene source

[Fe(N4Py)(CH3CN)](ClO4)2 can efficiently catalyze intermolecular nitrene insertion of sp3 C-H bonds with bromamine-T as the nitrene source, forming the desired tosylprotected amines with NaBr as the by-product.