222845-24-1

Basic information

• Product Name: (3aR,5R,6S,6aR)-5-[(R)-2-Benzyloxy-1-(4-methoxy-benzyloxy)-ethyl]-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole
• Synonyms: (3aR,5R,6S,6aR)-5-[(R)-2-Benzyloxy-1-(4-methoxy-benzyloxy)-ethyl]-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole
• CAS NO: 222845-24-1
• Molecular Weight: 550.649
• Mol File: 222845-24-1.mol

Chemical Properties

• CAS DataBase Reference: (3aR,5R,6S,6aR)-5-[(R)-2-Benzyloxy-1-(4-methoxy-benzyloxy)-ethyl]-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,5R,6S,6aR)-5-[(R)-2-Benzyloxy-1-(4-methoxy-benzyloxy)-ethyl]-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole(222845-24-1)
• EPA Substance Registry System: (3aR,5R,6S,6aR)-5-[(R)-2-Benzyloxy-1-(4-methoxy-benzyloxy)-ethyl]-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole(222845-24-1)

Safety Data

• Hazardous Substances Data: 222845-24-1(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 824-94-2 p-methoxybenzyl chloride 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 222845-47-8 (3aR,5R,6S,6aR)-5-[(R)-1,2-Bis-(4-methoxy-benzyloxy)-ethyl]-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 18549-40-1 1,2-O-isopropylidene-α-D-glucofuranose 

Relevant articles and documents

Regioselective deprotection of p-methoxybenzyl ethers of furanose derivatives

Reaction of per-p-methoxybenzylated hexofuranoses and pentofuranoses with either a catalytic amount of tin chloride dihydrate (SnCl2·2H2O) or 0.5-10% solution of trifluoroaoetic acid in dichloromethane afforded regioselectively the corresponding monosaccharide derivatives having a single free hydroxyl group at C(5) in good yields.