22293-38-5

Basic information

• Product Name: N-acetyl-1,2-diphenylhydrazine
• Synonyms: N-acetyl-1,2-diphenylhydrazine
• CAS NO: 22293-38-5
• Molecular Formula: C₁₄H₁₄N₂O
• Molecular Weight: 226.28
• Mol File: 22293-38-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 342.5°Cat760mmHg
• Flash Point: 161°C
• Appearance: /
• Density: 1.201g/cm³
• CAS DataBase Reference: N-acetyl-1,2-diphenylhydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: N-acetyl-1,2-diphenylhydrazine(22293-38-5)
• EPA Substance Registry System: N-acetyl-1,2-diphenylhydrazine(22293-38-5)

Safety Data

• Hazardous Substances Data: 22293-38-5(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 122-66-7 diphenyl hydrazine 
• 75-36-5 acetyl chloride 
• 64-17-5 ethanol 
• 861324-53-0 acetic acid-(N'-nitroso-N,N'-diphenyl-hydrazide) 
• 7803-57-8 hydrazine hydrate 
• 64-19-7 acetic acid 
• 60-29-7 diethyl ether 
• 127-17-3 2-oxo-propionic acid 
• 1227476-15-4 Azobenzene 
• 591-50-4 iodobenzene 
• 114-83-0 1-acetyl-2-phenylhydrazine 
• 3451-88-5 1,1'-Diacetyl-1,1',4,4'-tetrahydro-4,4'-bipyridine 
• 100-65-2 N-Phenylhydroxylamine 

Downstream Products

• 4471-10-7 N,N'-(biphenyl-4,4'-diyl)dibenzamide 
• 50-33-9 Phenylbutazone 
• 3366-61-8 N-acetylbenzidine 
• 861367-73-9 1,4-diacetyl-1,2,3,4-tetraphenyl-tetrazane 
• 60544-72-1 [1,4]benzoquinone-mono-[phenyl-(4-phenylazo-phenyl)-hydrazone] 
• 40395-24-2 N-Ethylhydrazobenzol 
• 103-69-5 N-ethyl-N-phenylamine 
• 6049-42-9 N,N'-diacetyl-N,N'-diphenylhydrazine 
• 103-84-4 Acetanilid 
• 1227476-15-4 Azobenzene 
• 62-53-3 aniline 
• 861324-53-0 acetic acid-(N'-nitroso-N,N'-diphenyl-hydrazide) 

Relevant articles and documents

Visible-Light-Mediated Hydroacylation of Azobenzenes with α-Keto Acids

A visible-light-mediated protocol for the hydroacylation of azobenzenes with α-keto acids has been developed. In the absence of any catalyst or additive, decarboxylative hydroacylation proceeded smoothly under visible-light irradiation at room temperature. A wide range of azobenzenes and α-keto acids were well-tolerated and afforded hydroacylation products in high to excellent yields. Preliminary investigations indicated that photoactive azobenzenes absorb visible light to enable the transformation.

Reduction of Ag(I) by 1-acyl-2-arylhydrazines: Mechanism of photographic infectious development

The photographic process of 'infectious development' in which 1-acyl-2-arylhydrazines reduce Ag(I) has been studied using analogues. 1-Acyl-2-aryldiazenes, resulting from oxidation of 1-acyl-2-arylhydrazines, are hydrolysed to anions of aryldiazenes (ArN = NH), which undergo further oxidation with loss of nitrogen to yield aryl radicals. The aryl radicals cause 'feedback inhibition' which is prevented by the addition of benzhydrol.

NAD(P)H and Acetyl-CoA Models: Part I - Reaction of Nitrosobenzene with 1,1'-Diacetyl-1,1',4,4'-tetrahydro-4,4'-bipyridine

In vivo metabolic conditions of coenzymes NAD(P)H and acetyl-CoA may be simulated in 1,1'-diacetyl-1,1',4,4'-tetrahydro-4,4'-bipyridine (DTB) loosing hydride ion with concomitant loss of acetyl cation.This is illustrated by the formation of almost same products on treatment of nitrosobenzene with DTB as formed in vivo.The simultaneous loss of hydride and acetyl cation by DTB converts nitrosobenzene to activated labile intermediate O-acetylphenylhydroxylamine (12) which has been considered responsible for the origin of majority of products.