THE PRACTICAL PROCEDURE FOR A PREPARATION OF 1-CHLOROALKYL p-TOLYL SULFOXIDES IN HIGH OPTICALLY ACTIVE FORM: A VERY SHORT SYNTHESIS OF OPTICALLY ACTIVE DISPARLURE

DOI: 10.1016/S0040-4039(00)80083-0

Source and publish data:

Tetrahedron Letters p. 313 - 316 (1988)

Update date:2022-08-04

Topics:

Authors:

Satoh, Tsuyoshi

Oohara, Teruhiko

Ueda, Yoshiko

Yamakawa, Koji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80083-0

A chlorination of optically active alkyl p-tolyl sulfoxides with N-chlorosuccinimide in dichloromethane in the presence of potassium carbonate afforded optically active 1-chloroalkyl p-tolyl sulfoxides in 87-94percent ee (88-94percent chemical yields).The optically active chloroalkyl sulfoxide was applied to a synthesis of optically active (+)-disparlure.

Full text of DOI:10.1016/S0040-4039(00)80083-0

Products guided by the article

Product name:1-((R)-1-Chloro-undecane-1-sulfinyl)-4-methyl-benzene

Cas No:223392-45-8

R&D Labs maybe for 223392-45-8

Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China

Relevant to this article

Enantioselective synthesis of binaphthol derivatives by oxidative coupling of naphthol derivatives catalyzed by chiral diamine-copper complexes

Doi:10.1021/jo981808t
(1999)
A RuH₂(CO)(PPh₃)₃-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage

Doi:10.1021/ja043334n
(2005)
Synthesis of multi-1,10-phenanthroline ligands with 1,3-phenylene linkers and their lithium complexes

Doi:10.1002/chem.200401264
(2005)
Doi:10.1021/jo00827a045
(1970)
Cyclic dipeptides. 3.¹ Synthesis of methyl (R)-6-[(tert- butoxycarbonyl)amino]-4,5,6,7-tetrahydro-2-methyl-5-oxo-1,4-thiazepine-3- carboxylate and its hexahydro analogues: Elaboration of a novel dual ACE/NEP inhibitor

Doi:10.1021/jo981425v
(1999)
Synthesis of the ligand N,N′-bis(2-tert-butylthiobenzenylidene)-diethylenetriamine; Its reactivity with nickel(II) salts

Doi:10.1016/S0020-1693(98)00406-X
(1999)

Article Doi