THE PRACTICAL PROCEDURE FOR A PREPARATION OF 1-CHLOROALKYL p-TOLYL SULFOXIDES IN HIGH OPTICALLY ACTIVE FORM: A VERY SHORT SYNTHESIS OF OPTICALLY ACTIVE DISPARLURE

DOI: 10.1016/S0040-4039(00)80083-0

Source and publish data:

Tetrahedron Letters p. 313 - 316 (1988)

Update date:2022-08-04

Topics:

Authors:

Satoh, Tsuyoshi

Oohara, Teruhiko

Ueda, Yoshiko

Yamakawa, Koji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)80083-0

A chlorination of optically active alkyl p-tolyl sulfoxides with N-chlorosuccinimide in dichloromethane in the presence of potassium carbonate afforded optically active 1-chloroalkyl p-tolyl sulfoxides in 87-94percent ee (88-94percent chemical yields).The optically active chloroalkyl sulfoxide was applied to a synthesis of optically active (+)-disparlure.

Full text of DOI:10.1016/S0040-4039(00)80083-0

Products guided by the article

Product name:1-((R)-1-Chloro-undecane-1-sulfinyl)-4-methyl-benzene

Cas No:223392-45-8

R&D Labs maybe for 223392-45-8

Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Suzhou Sibian Chemical Technology Co., Ltd

website:http://www.sibianpharm.com

Contact:+8618169181984,+8618013186906

Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
Beijing Green Guardee Technology CO,.LTD

Contact:+86-10-69706062

Address:F2 BLdj,5 No.37 Chaoqian Road
NINGBO YINZHOU PRECISE COLOR CO.,LTD.

Contact:86-574-88139809 86-574-83033159

Address:Qiming Road,Yinzhou,Ningbo,China

Relevant to this article

Enantioselective synthesis of binaphthol derivatives by oxidative coupling of naphthol derivatives catalyzed by chiral diamine-copper complexes

Doi:10.1021/jo981808t
(1999)
A RuH₂(CO)(PPh₃)₃-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage

Doi:10.1021/ja043334n
(2005)
Synthesis of multi-1,10-phenanthroline ligands with 1,3-phenylene linkers and their lithium complexes

Doi:10.1002/chem.200401264
(2005)
Doi:10.1021/jo00827a045
(1970)
Cyclic dipeptides. 3.¹ Synthesis of methyl (R)-6-[(tert- butoxycarbonyl)amino]-4,5,6,7-tetrahydro-2-methyl-5-oxo-1,4-thiazepine-3- carboxylate and its hexahydro analogues: Elaboration of a novel dual ACE/NEP inhibitor

Doi:10.1021/jo981425v
(1999)
Synthesis of the ligand N,N′-bis(2-tert-butylthiobenzenylidene)-diethylenetriamine; Its reactivity with nickel(II) salts

Doi:10.1016/S0020-1693(98)00406-X
(1999)

Article Doi