Tetrahedron Letters p. 313 - 316 (1988)
Update date:2022-08-04
Topics:
Satoh, Tsuyoshi
Oohara, Teruhiko
Ueda, Yoshiko
Yamakawa, Koji
A chlorination of optically active alkyl p-tolyl sulfoxides with N-chlorosuccinimide in dichloromethane in the presence of potassium carbonate afforded optically active 1-chloroalkyl p-tolyl sulfoxides in 87-94percent ee (88-94percent chemical yields).The optically active chloroalkyl sulfoxide was applied to a synthesis of optically active (+)-disparlure.
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