223582-33-0

Upstream product

• 627466-64-2 2,3,4,6-tetra-O-benzoyl-D-glucopyranose 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 62-50-0 Ethyl methanesulfonate 

Downstream Products

• 223582-41-0 C₃₇H₄₀O₈S 
• 1319716-01-2 2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-ethoxysulfonyl-D-glucohept-2-enitol 
• 1319716-00-1 3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethoxysulfonyl-α-D-glucohept-2-ulopyranosyl chloride 
• 1319715-99-5 3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethoxysulfonyl-α-D-glucohept-2-ulopyranosyl bromide 
• 1319716-08-9 4-methoxyphenyl 2,3,6-tri-O-benzyl-4-O-(3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethoxysulfonyl-α-D-glucohept-2-ulopyranosyl)-β-D-glucopyranoside 
• 223582-39-6 methyl 2,6-di-O-benzyl-3-O-(3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethylsulfonato-α-D-gluco-hept-2-ulopyranosyl)-β-D-galactopyranoside 
• 223582-35-2 ethyl 3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethylsulfonato-2-thio-α-D-gluco-hept-2-ulopyranoside 

Relevant academic research and scientific papers

Facile synthesis of conjugated exo-glycals

Two efficient methods were explored for the synthesis of various conjugated exo-glycals: (i) by nucleophilic addition of sugar lactones with a subsequent dehydration, and (ii) by selenylation of C-glycosides with subsequent selenoxide elimination. These reactions occurred in a stereoselective manner to give exclusively or predominantly the (Z)-isomers of exo-glycals.

Sulfonic acid analogues of the sialyl Lewis X tetrasaccharide

Sulfonomethyl mimics of 2-ulosonic acids were prepared by addition of the ethyl methanesulfonate carbanion on aldonolactone derivatives, and these were converted into new analogues of the sialyl Lewis X tetrasaccharide. Copyright (C) 2000 Elsevier Science Ltd.

Sulfonomethyl analogues of aldos-2-ulosonic acids. Synthesis of a new sialyl Lewis X analogue

Sulfonomethyl derivatives of aldos-2-ulosonic acids have been synthesized by addition of the ethyl methanesulfonate carbanion to aldonolactones. A sulfonylated mimic molecule of the sialyl Lewis X tetrasaccharide has been prepared by using a new sulfonomethyl ulosonic acid analogue.