627466-64-2

Basic information

• Product Name: 2,3,4,6-tetra-O-benzoyl-D-glucopyranose
• Synonyms: 2,3,4,6-tetra-O-benzoyl-D-glucopyranose
• CAS NO: 627466-64-2
• Molecular Weight: 596.59
• Mol File: 627466-64-2.mol
• Article Data: 45

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzoyl-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzoyl-D-glucopyranose(627466-64-2)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzoyl-D-glucopyranose(627466-64-2)

Safety Data

• Hazardous Substances Data: 627466-64-2(Hazardous Substances Data)

Upstream product

• 105376-04-3 ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside 
• 2592-58-7 1,2,3,4,6-penta-O-benzoyl-D-glucopyranoside 
• 492-61-5 β-D-glucose 
• 14218-11-2 2,3,4,6-tetra-O-benzoylglucosyl bromide 
• 79134-70-6 N-Benzyloxycarbonyl-L-serine 2-bromoethyl ester 
• 572-09-8 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl bromide 
• 339276-12-9 2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl 1-(N-phenyl)-2,2,2-trifluoroacetimidate 
• 151767-11-2 2,3,4,5-tetra-O-benzoyl-D-glucopyranosyl trichloroacetimidate 
• 2280-44-6 D-Glucose 
• 98-88-4 benzoyl chloride 
• 1423987-57-8 C₃₆H₃₃NO₁₀ 
• 2592-58-7 1,2,3,4,6-penta-O-benzoyl-β-D-glucopyranose 
• 1095998-16-5 C₄₀H₃₃NO₉S 
• 14262-85-2 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl iodide 

Downstream Products

• 14218-11-2 2,3,4,6-tetra-O-benzoylglucosyl bromide 
• 953397-00-7 2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl 1-H-phosphonate 
• 286860-87-5 (1(1')-Z)-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(ethoxysulfonyl)methylidene-D-glucopyranose 
• 223582-33-0 3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethoxysulfonyl-α-D-glucohept-2-ulopyranose 
• 223582-35-2 ethyl 3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethylsulfonato-2-thio-α-D-gluco-hept-2-ulopyranoside 
• 223582-39-6 methyl 2,6-di-O-benzyl-3-O-(3,4,5,7-tetra-O-benzyl-1-deoxy-1-ethylsulfonato-α-D-gluco-hept-2-ulopyranosyl)-β-D-galactopyranoside 
• 1038411-44-7 perbenzoyl-β-D-glucopyranosyl o-(1-hexynyl)benzoate 
• 1038411-36-7 perbenzoyl-α-D-glucopyranosyl o-(1-hexynyl)benzoate 

Relevant articles and documents

A novel and efficient deprotection of the allyl group at the anomeric oxygen of carbohydrates

Perfluoroalkylation with perfluoroalkyl iodide under sodium dithionite and sodium bicarbonate in acetonitrile/water followed by elimination in the presence of zinc powder and ammonium chloride in ethanol was disclosed to be an extremely mild and efficient procedure for deprotection of the anomeric allyl group of carbohydrates.

Ionic liquid-assisted catalysis for glycosidation of two triterpenoid sapogenins

In order to both investigate the universality of ionic liquid-based catalytic systems for synthesis of triterpene saponins and explore their effective application methods together with the catalytic behaviors of ionic liquids in related reactions by comparison between different initiators, oleanolic acid and ursolic acid were selected to establish a catalytic system for glycosylation in this study as typical representatives of pentacyclic triterpene sapogenins. As a result, it was found that the system of [C4mim][OTf] + TMSOTf in the reactions between the glycosyl receptors and donors showed obvious catalytic effects; also, the system was stable and could be recycled. The functions of IL include solvent, cocatalyst and stabilizer, simultaneously; thus, the current catalytic system is greener, simpler and more efficient. The reaction time was short, and only β-type products were obtained. This study offers a reference for developing a new glucoside synthesis technology and provides sufficient preliminary exploration and basic data for further large-scale applications.

Aralia elata seem monomer saponin derivative and preparation method and use thereof

The invention discloses an aralia elata seem monomer saponin derivative and a preparation method and use thereof. The derivative has a structure represented by a general formula (I). Oleanolic acid orursolic acid, five kinds of sugars and caffeic acid are