2243-67-6Relevant articles and documents
Synthesis of Stable Thiazole-Linked Covalent Organic Frameworks via a Multicomponent Reaction
Wang, Kewei,Jia, Zhifang,Bai, Yang,Wang, Xue,Hodgkiss, Sophie E.,Chen, Linjiang,Chong, Samantha Y.,Wang, Xiaoyan,Yang, Haofan,Xu, Yongjie,Feng, Feng,Ward, John W.,Cooper, Andrew I.
, p. 11131 - 11138 (2020/07/13)
The development of robust synthetic routes to stable covalent organic frameworks (COFs) is important to broaden the range of applications for these materials. We report here a simple and efficient three-component assembly reaction between readily available aldehydes, amines, and elemental sulfur via a C-H functionalization and oxidative annulation under transition-metal-free conditions. Five thiazole-linked COFs (TZ-COFs) were synthesized using this method. These materials showed high levels of crystallinity, high specific surface areas, and excellent physicochemical stability. The photocatalytic applications of TZ-COFs were investigated, and TZ-COF-4 gave high sacrificial hydrogen evolution rates from water (up to 4296 μmol h-1 g-1 under visible light irradiation) coupled with high stability and recyclability, with sustained hydrogen evolution for 50 h.
Intramolecular interactions in diiodonaphthalenes
Novak, Igor,Jiang, Huiming,Kovac, Branka
, p. 480 - 484 (2007/10/03)
The synthesis and the electronic structure of isomeric di-iodonaphthalenes is described. The electronic structure has been investigated by HeI/HeII photoelectron spectroscopy and non-Koopmans' quantum chemical calculations. The influence of the topology of iodine substitution on the electronic structure is discussed. Special emphasis is placed on elucidating the role of intramolecular iodine-iodine interactions.