225-61-6Relevant articles and documents
Oxidative skeletal rearrangement of 1,1′-binaphthalene-2,2′- diamines (BINAMs) via C-C bond cleavage and nitrogen migration: A versatile synthesis of U-shaped azaacenes
Takeda, Youhei,Okazaki, Masato,Minakata, Satoshi
supporting information, p. 10291 - 10294 (2014/08/18)
An oxidative skeletal rearrangement of 1,1′-binaphthalene-2,2′- diamines (BINAMs) that involves the cleavage of a strong C-C single bond of the binaphthalene unit and the nitrogen migration has been discovered. The unprecedented rearrangement enables access to a series of U-shaped azaacenes otherwise difficult to prepare in a selective manner by classical methods. Moreover, physicochemical properties of the unique azaacenes have been comprehensively investigated. This journal is the Partner Organisations 2014.