22719-43-3Relevant articles and documents
Kuzmin et al.
, p. 495 (1977)
Mukai et al.
, p. 641 (1977)
Temperature and Pressure Effects on the Reversible Reaction of a Parent Phenol (GH) Corresponding to Galvinoxyl with Aliphatic Amines
Nishimura, Norio,Iga, Siroh,Satoh, Masahiro,Yamamoto, Shunzo
, p. 2437 - 2441 (2007/10/02)
The effects of temperature and pressure on the reversible reaction between GH and aliphatic amines in acetonitrile have been studied spectrophotometrically.The formation of the free ions rather than that of ion pairs has been confirmed by the modified Benesi-Hildebrand (B-H) plot.From the plot the equilibrium constants were estimated.From the temperature dependence of the equilibrium constant (K), the heat and entropy of reactions were estimated to be: (ΔH0)av=-44.5 kJ mol-1, and (ΔS0)av=-193 J K-1 mol-1.From the pressure dependence of K the reaction volume (ΔV0)av was estimated to be -40 dm3 mol-1.When unbranched primary amines were used, a side reaction took place for which an explanation has been given.
2,3',5',6-Tetra-t-butylindophenoxyl, competitive scavenging, and isoope effects.
Bartlett,Purrington
, p. 3303 - 3309 (2007/10/06)
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