22810-79-3Relevant academic research and scientific papers
Gas-phase calorimetry of trimethyl group Va bases with boron Lewis acids
Mente, Donald C.,Mills, Jerry L.,Mitchell, Roy E.
, p. 123 - 126 (1975)
The reaction between the group Va Lewis bases trimethylphosphine, trimethylarsine, and trimethylstibine and the boron Lewis acids boron trifluoride, boron trichloride, boron tribromide, diborane, and trimethylborane has been studied using gas-phase calori
Synthesis and spectroscopic studies of antimony pentachloride complexes with neutral oxygen, sulfur and selenium ligands
Corcoran, Sarah M.,Levason, William,Patel, Rina,Reid, Gillian
, p. 1263 - 1268 (2008/10/09)
The compounds [SbCl5(R3EY)] (R = Me or Ph; E = P or As; Y = O or S) have been prepared from SbCl5 and the appropriate ligand in CH2Cl2 or CCl4 solutions, and characterised by analysis, IR,
Synthesis, molecular structure, and isomerisation in solution of (ME 3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony
Beckmann, Jens,Dakternieks, Dainis,Duthie, Andrew,Foitzik, Richard C.
, p. 1508 - 1510 (2008/10/08)
The reaction of Me3SbCl2 and (Me2SnS) 3 afforded the complex (Me3SbS)2Me 2SnCl2 in high yields, whose molecular structure features both hypercoordinated tin and antimony atoms. In solution, (Me 3SbS)2Me2SnCl2 undergoes a reversible dissociation and ligand interchange reaction to give Me 3SbS, Me3SbCl2 and (Me2SnS) 3.
Syntheses of antimony(V) derivatives from trimethyl and triphenylantimony(III), dihydric phenols, and tert-butyl hydroperoxide
Dodonov, V. A.,Fedorov, A. Yu.,Usyatinsky, R. I.,Zaburdyaeva, S. N.,Gushchin, A. V.
, p. 730 - 733 (2007/10/02)
Trimethyl and triphenylantimony o-phenylene dioxides were obtained by the reaction of trimethyl- and triphenylantimony with pyrocatechol in the presence of tert-butyl hydroperoxide in 68 and 81percent yields, respectively. 7,7,7,15,15,15-hexamethyl-(and p
Alkylantimondichloride und -bromide
Ates, Mustafa,Breunig, Hans Joachim,Guelec, Sabahittin
, p. 67 - 72 (2007/10/02)
MeSbCl2 is formed by the exchange reaction of equimolar amounts of Me2SbCl with SbCl3.Alkylantimony dibromides of the type RSbBr2 with R = Me, Et, n-Pr, n-Bu are obtained by dismutation of the corresponding dialkylantimony bromides with SbBr3.Exchange as
Preparation and 121Sb M?ssbauer spectroscopy of methylchlorostibines
Stevens,Trooster,Meinema,Noltes
, p. 801 - 803 (2008/10/08)
The synthesis and 121Sb M?ssbauer spectra are reported for CH3SbCl2 and (CH3)2SbCl. The M?ssbauer spectroscopic data for the series (CH3)xSbCl3-x with x = 0-3 are discussed. The quadrupole coupling parameters of all four compounds can be explained qualitatively with a simple point charge model, assuming the bond angles between the ligands to be close to 90°. The isomer shift data indicate a decrease of s-electron density at the Sb nucleus with increase of x, which is ascribed to an increase of p character of the lone-pair electrons.
The chloramination of some substituted stibines
McKenney, Robert L.,Sisler, Harry H.
, p. 1178 - 1182 (2007/10/18)
Trimethyl-, triethyl-, tri-n-propyl-, tri-n-butyl-, and triphenylstibines react with ammonia-free chloramine or an ammonia-chloramine mixture to produce compounds of the type [R3Sb(Cl)]2NH (I). These compounds readily hydrolyze to [R3Sb-(Cl)]2O (II ). Further reactions of II are also described. Infrared and proton magnetic resonance studies were carried out on compounds of types I and II and on a variety of other antimony compounds. Qualitative assignments of infrared bands are given.
