2294-93-1

Basic information

• Product Name: 1,2,2-TRIPHENYLETHANOL
• Synonyms: 1,2,2-TRIPHENYLETHANOL
• CAS NO: 2294-93-1
• Molecular Formula: C₂₀H₁₈O
• Molecular Weight: 274.35632
• Mol File: 2294-93-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2,2-TRIPHENYLETHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,2-TRIPHENYLETHANOL(2294-93-1)
• EPA Substance Registry System: 1,2,2-TRIPHENYLETHANOL(2294-93-1)

Safety Data

• Hazardous Substances Data: 2294-93-1(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 359-06-8 monofluoroacetyl chloride 
• 453-18-9 methyl fluoroacetate 
• 100-52-7 benzaldehyde 
• 90-99-3 diphenylchloromethane 
• 6566-38-7 cis-1,2-dihydroxy-1,2-dimethyl-1,2-dihydroacenaphthalene 
• 17763-67-6 Phenyl triflate 
• 591-51-5 phenyllithium 
• 947-91-1 Diphenylacetaldehyde 
• 100-59-4 phenylmagnesium chloride 
• 299159-57-2 1-[(benzhydryloxy)methyl]1H-1,2,3-benzotriazole 
• 29240-44-6 2-bromo-1,1,2-triphenyl-ethanol 
• 79-04-9 chloroacetyl chloride 
• 4479-98-5 2,2,3-triphenyloxirane 

Downstream Products

• 58-72-0 Triphenylethylene 
• 1607-57-4 Triphenylvinyl bromide 
• 50915-76-9 1-chloro-1,2,2-triphenyl-ethane 
• 1165950-66-2 (1,2,2-triphenyl-1-ethoxy)trimethylsilane 
• 18495-77-7 1-bromo-1,2,2-triphenylethane 
• 95625-69-7 (+/-)-acetic acid-(1,2,2-triphenyl-ethyl ester) 
• 106041-85-4 (+/-)-succinic acid mono-(1,2,2-triphenyl-ethyl ester) 

Relevant articles and documents

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Asymmetrie allylation of methyl ketones by using chiral phenyl carbinols

Novel chiral auxiliaries for the stereoselective allylation of aliphatic methyl ketones with allyltrimethylsilane and their use in the synthesis of homoallylic ethers are described. In a multicomponent domino process catalyzed by trifluoromethanesulfonic

Silver catalyzed zinc Barbier reaction of benzylic halides in water

Benzylic chlorides react in aqueous dibasic potassium phosphate under silver catalysis with aromatic aldehydes in the presence of zinc dust to give 1,2-diaryl alcohols in moderate to good yields. Dimerization to bibenzyls and reduction of the halide are important side reactions. A wide range of substituted aromatic and heteroaromatic aldehydes and of substituted benzylic chlorides can be used. Aliphatic aldehydes and ketones are unreactive. A mechanism of two SET on the metal surface is discussed.