23049-84-5Relevant academic research and scientific papers
Palladium-Catalyzed Desulfurative Hiyama Coupling of Thioureas to Achieve Amides via Selective C-N Bond Cleavage
He, Zhanyu,Yan, Chu,Zhang, Mei,Irfan, Majeed,Wang, Zijia,Zeng, Zhuo
supporting information, p. 705 - 710 (2021/10/25)
Palladium-catalyzed Hiyama coupling of active thioureas via selective C-N bond cleavage is reported. Notably, the new approach employed active thioureas as coupling partners in the presence of arylsilanes to give amides in good yield. Further, this strategy, which utilized CuF 2as a key oxidant and activator, afforded various amide products under mild conditions and an easy to handle procedure without extra base.
Mild Acetylation of Amides, Thiamides, Ureas, and Thioureas Using Methyl Bis(1-naphthyl)bismuthinate in Acetic Acid
Ogawa, Takuji,Miyazaki, Kikuko,Suzuki, Hitomi
, p. 1651 - 1654 (2007/10/02)
Amides, thioamides, ureas, and thioureas were N-acetylated in good yield with acetic acid in the presence of methyl bis(1-naphthyl)bismuthinate at room tempereature.
