23063-65-2

Basic information

• Product Name: 1-chloro-4-(2-methylallyl)benzene
• Synonyms: 1-Chloro-4-(2-methyl-2-propenyl)benzene
• CAS NO: 23063-65-2
• Molecular Formula: C₁₀H₁₁Cl
• Molecular Weight: 166.65
• EINECS: 245-406-0
• Mol File: 23063-65-2.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 215.2°C at 760 mmHg
• Flash Point: 84.9°C
• Appearance: /
• Density: 1.028g/cm³
• Vapor Pressure: 0.219mmHg at 25°C
• Refractive Index: 1.523
• CAS DataBase Reference: 1-chloro-4-(2-methylallyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-4-(2-methylallyl)benzene(23063-65-2)
• EPA Substance Registry System: 1-chloro-4-(2-methylallyl)benzene(23063-65-2)

Safety Data

• Hazardous Substances Data: 23063-65-2(Hazardous Substances Data)

Usage

General Description

1-Chloro-4-(2-methylallyl)benzene, also known as p-chloro-α-methylallylbenzene, is an organic compound with the chemical formula C10H11Cl. It is a clear, colorless liquid that is insoluble in water but soluble in organic solvents. This chemical is primarily used as an intermediate in the production of pharmaceuticals, agrochemicals, and other organic compounds. It is also used as a fragrance ingredient and flavoring agent in the food and beverage industry. The compound is known for its strong, aromatic odor and is commonly used in the production of perfumes and other fragrance products. It is important to handle 1-Chloro-4-(2-methylallyl)benzene with caution, as it is flammable and can cause irritation to the skin, eyes, and respiratory system upon exposure.

InChI:InChI=1/C10H11Cl/c1-8(2)7-9-3-5-10(11)6-4-9/h3-6H,1,7H2,2H3

Upstream product

• 106-39-8 bromochlorobenzene 
• 563-47-3 3-Chloro-2-methylpropene 
• 18503-93-0 1-chloro-4-(β-chloro-isobutyl)-benzene 
• 920-39-8 isopropylmagnesium bromide 
• 104-88-1 4-chlorobenzaldehyde 
• 64-19-7 acetic acid 
• 1432-31-1 (4-chlorophenyl)dimethylsilane 
• 19366-15-5 4-chloro-β,β-dimethylstyrene 
• 1679-18-1 4-Chlorophenylboronic acid 
• 513-42-8 3-hydroxy-2-methyl-1-propene 
• 1217863-25-6 [2-(hydroxymethyl)phenyl]dimethyl(4-chlorophenyl)silane 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 

Downstream Products

• 55706-98-4 2-methyl-3-(4-chlorophenyl)-2-propenyl thiocyanate 
• 106119-23-7 2-(4-chlorobenzyl)-2-propenyl thiocyanate 
• 106119-30-6 2-(4-chlorobenzyl)-2-propenyl isothiocyanate 
• 106119-22-6 2-acetoxy-2-methyl-3-(4-chlorophenyl)propyl thiocyanate 
• 106119-24-8 2-methyl-1-(4-chlorophenyl)-2-propenyl isothiocyanate 
• 78558-98-2 N-Formyl-1.1-dimethyl-2-<4-chlor-phenyl>-aethylamin 

Relevant articles and documents

Catalytic, contra-Thermodynamic Positional Alkene Isomerization

The positional isomerization of C═C double bonds is a powerful strategy for the interconversion of alkene regioisomers. However, existing methods provide access to thermodynamically more stable isomers from less stable starting materials. Here, we report

Copper(I) 2-hydroxyethoxide-promoted cross-coupling of aryl- and alkenyldimethylsilanes with organic halides

Fluoride-free cross-coupling of aryl- and alkenyldimethylsilanes with organic halides proceeded in the presence of monocopper(I) alkoxide of ethylene glycol.

Studies on the synthesis of chiral 2-(p.chlorophenyl)-3-methylbutanoic acid, a key-precursor of Fenvalerate, by hydrocarbonylation reactions

The preparation of racemic 2-(p.chlorophenyl)-3-methylbutanoic acid (2), a building block for (S,S)-Fenvalerate (an important broad spectrum insecticide), was effected by rhodium catalyzed hydroformylation of 2-methyl-1 -(p.chlorophenyl) propene (4) in the presence of excess of triphenylphosphine to inhibit substrate isomerization followed by mild oxidation of the resulting aldehyde 6; an overall yield of 88% was reached. Olefin 4 exhibits a very low tendency to undergo both hydrocarboethoxylation and hydrocarboxylation in the presence of palladium complexes as catalysts. Enantioselective hydrocarbonylation reactions carried out on olefin 4 afford unsatisfactory chemical and optical yields of the optically active ester 5 or acid 2. Springer-Verlag 1996.