2316-84-9Relevant articles and documents
A highly chemoselective Mukaiyama aldol reaction of saturated aldehyde over unsaturated aldehyde with enol tris(2,6-diphenylbenzyl)silyl ether
Shirakawa, Seiji,Maruoka, Keiji
, p. 1469 - 1472 (2002)
An exceedingly high chemoselective Mukaiyama aldol reaction of saturated aldehydes in the presence of unsaturated aldehydes (benzaldehyde and α,β-enals) has been realized for the first time by using the structurally unique enol tris(2,6-diphenylbenzyl)sil
Improved conditions for the proline-catalyzed aldol reaction of acetone with aliphatic aldehydes
Martínez, Alberto,Zumbansen, Kristina,D?hring, Arno,Van Gemmeren, Manuel,List, Benjamin
supporting information, p. 932 - 934 (2014/05/06)
The proline-catalyzed asymmetric aldol reaction between aliphatic aldehydes and acetone has, to date, remained underdeveloped. Challenges in controlling this reaction include avoiding undesired side reactions such as aldol condensation and self-aldolization. In recent years we have developed optimized conditions, which enable high yields and good to excellent enantioselectivities, and which are presented in this communication. Georg Thieme Verlag Stuttgart New York.
Ti-catalyzed reformatsky-type coupling between α-halo ketones and aldehydes
Estevez, Rosa E.,Paradas, Miguel,Millan, Alba,Jimenez, Tania,Robles, Rafael,Cuerva, Juan M.,Oltra, J. Enrique
, p. 1616 - 1619 (2008/09/16)
(Chemical Equation Presented) We describe the first Ti-catalyzed Reformatsky-type coupling between α-halo ketones and aldehydes. The reaction affords β-hydroxy ketones under mild, neutral conditions compatible with ketones and other electrophiles. The cat
