23183-95-1Relevant articles and documents
NEW (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES AND A NEW CATALYTIC METHOD FOR OBTAINING NEW AND CONVENTIONAL SUBSTITUTED (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES
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Page/Page column 0110; 0154-0160, (2014/02/15)
The present invention relates to new (triorganosilyl)alkynes and their derivatives having general formula 1 R1—C≡C—Z (I) In its second aspect, this invention relates to a new selective method for the preparation of new and conventional (triorga
Silylative coupling of terminal alkynes with iodosilanes: New catalytic activation of sp-hybridized carbon-hydrogen bonds
Kownacki, Ireneusz,Marciniec, Bogdan,Dudziec, Beata,Kubicki, MacIej
experimental part, p. 2539 - 2545 (2011/06/27)
The [{Ir(μ-Cl)(CO)2}2] (I)-catalyzed reaction of terminal alkynes and diynes with Me3SiI with the aid of NEt(i-Pr)2 occurs smoothly, leading to the formation of mono- and bis-silyl-functionalized alkynyl derivat