23197-69-5

Basic information

• Product Name: DIETHYL 4-ETHOXYPHENYLMALONATE
• Synonyms: DIETHYL 4-ETHOXYPHENYLMALONATE;(p-Ethoxyphenyl)Malonic Acid Diethyl Ester;2-(4-Ethoxyphenyl)propanedioic Acid 1,3-Diethyl Ester
• CAS NO: 23197-69-5
• Molecular Formula: C₁₅H₂₀O₅
• Molecular Weight: 280.3163
• Product Categories: Aromatics Compounds;Aromatics
• Mol File: 23197-69-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• Solubility: Chloroform, Ethyl Acetate, Methanol
• CAS DataBase Reference: DIETHYL 4-ETHOXYPHENYLMALONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIETHYL 4-ETHOXYPHENYLMALONATE(23197-69-5)
• EPA Substance Registry System: DIETHYL 4-ETHOXYPHENYLMALONATE(23197-69-5)

Safety Data

• Hazardous Substances Data: 23197-69-5(Hazardous Substances Data)

Usage

Chemical Properties

Pale-Yellow Oil

Uses

Diethyl 4-Ethoxyphenylmalonate (cas# 23197-69-5) is a compound useful in organic synthesis.

Upstream product

• 156-38-7 4-hydroxyphenylacetate 
• 699-08-1 1-ethoxy-4-iodobenzene 
• 105-53-3 diethyl malonate 
• 40784-88-1 ethyl 4-ethoxyphenylacetate 
• 95-92-1 oxalic acid diethyl ester 

Downstream Products

• 95086-57-0 2-(p-ethoxyphenyl)-1,3-dibromopropane 
• 95086-59-2 2-(p-ethoxyphenyl)-1,3-propanedithiol 
• 95086-56-9 2-(p-ethoxyphenyl)-1,3-propanediol 

Relevant articles and documents

Mesogenic, optical, and dielectric properties of 5-substituted 2-[12-(4-pentyloxyphenyl)-p-carboran-1-yl] [1,3]dioxanes

Two homologous series of carborane-containing dioxanes 1[n] and 2[n] (n = 1-10) were prepared and their mesogenic properties investigated. All compounds exhibit nematic behavior and three members of series 2[n] show an E phase. Numerical analysis of the clearing temperatures gave a limiting value T NI(∞) of 89 °C for series 2[n] and indicated conformational flexibility of the dioxane ring. Investigations of three-ring derivative 1[4] gave Δn = 0.17, S = 0.53, and Δε = +0.4 ± 0.1 at 85 °C. Extrapolation of dielectric data for dilute solutions of 1[4] in 6-CHBT gave Δε = +0.4 ± 0.25 at 24 °C. Modelling of dielectric results with the Maier-Meier equation demonstrated that conformers with a higher β angle are preferred, which is consistent with conformational selection for the most elongated conformers. The Royal Society of Chemistry 2006.