2321-87-1Relevant academic research and scientific papers
New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes
Fu, Niankai,Song, Lu,Liu, Jinjian,Shen, Yifan,Siu, Juno C.,Lin, Song
, p. 14480 - 14485 (2019)
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new family of serine-derived chiral bisoxazolines with ancillary coordination sites were identified as optimal ligands.
Abnormal Ring Opening of 1,2-Epoxyalkyldiphenylphosphine Oxides with Lithium Aluminum Hydride to Form 2-Hydroxyalkyldiphenylphosphine Oxides
Imoto, Hiroyuki,Yamashita, Mitsuji
, p. 323 - 325 (2007/10/02)
Ring opening of 1,2-epoxyalkyldiphenylphosphine oxides with LiAlH4 gives 2-hydroxyalkyldiphenylphosphine oxides in good yield.This is the first example of ring opening of 1,2-epoxyalkyldiphenylphosphine oxides to give the corresponding 2-hydroxy derivativ
