2341-35-7Relevant academic research and scientific papers
Copper-mediated 1,2-bis(trifluoromethylation) of arynes
Yang, Xinkan,Tsui, Gavin Chit
, p. 8871 - 8875 (2018)
We herein describe an unprecedented 1,2-bis(trifluoromethylation) of arynes with [CuCF3] in the presence of an oxidant DDQ. The method allows the rapid construction of a new class of 1,2-bis(trifluoromethyl)arenes in one-step from aryne precurs
SYSTEM AND METHOD FOR FLUOROALKYLATED FLUOROPHTHALOCYANINES WITH AGGREGATING PROPERTIES AND CATALYTIC DRIVEN PATHWAY FOR OXIDIZING THIOLS
-
Page/Page column 10, (2012/05/20)
Organo-metallic materials with reduced steric hindrance and the ability to aggregate are disclosed. The metal remains capable of binding additional molecules. As an example, Zn complexes that prove aggregation are provided. Such aggregation may help impro
Cycloadditions and nucleophilic attack on Z-2H-Heptafluorobut-2-ene
Chambers, Richard D.,Edwards, Andrew R.
, p. 4949 - 4964 (2007/10/03)
Chemistry of Z-2H-Heptafluorobut-2-ene 1 is surveyed; cycloaddition reactions occur with a variety of benzenoid compounds, in some cases leading directly to aromatics. Addition to cyclopentadiene, followed by eliminations of hydrogen fluoride and ethyne, lead to isomeric bistrifluoromethylcyclopentadienes. Nucleophilic reactions occur readily with oxygen, nitrogen and sulphur nucleophiles and aniline provides a quinoline synthesis.
